1190 69 16302 6 54687 document 16302 SAXS_paper.zip application/zip 750e7c7c803d5ea1a55313ee1ee36b8e MD5 399101 2022-08-22 16:56:16 https://researchdata.bath.ac.uk/1190/1/SAXS_paper.zip 1190 1 1 application/zip other SAXS data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 2b in the paper. en public cc_by

SAXS_paper.zip

data 16303 6 54689 document 16303 XRD paper.zip application/zip 43233b36f0617cf2872724279ec26f06 MD5 245549 2022-08-22 17:08:37 https://researchdata.bath.ac.uk/1190/2/XRD%20paper.zip 1190 2 2 application/zip other XRD data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 1c & 5a and Table S1 & S2 in the paper and its supplementary information. en public cc_by

XRD paper.zip

data 16304 6 54691 document 16304 N2sorption_paper.zip application/zip e8dcac29d5d42b8a26ed0932989a55f8 MD5 35250 2022-08-22 17:21:40 https://researchdata.bath.ac.uk/1190/3/N2sorption_paper.zip 1190 3 3 application/zip other N₂ data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 2a & 5b in the paper. en public cc_by

N2sorption_paper.zip

data 16305 6 54693 document 16305 CO oxidation_paper.zip application/zip 4a16c3515adc715499fe2cb5f135beb9 MD5 2515522 2022-08-22 17:27:17 https://researchdata.bath.ac.uk/1190/4/CO%20oxidation_paper.zip 1190 4 4 application/zip other CO oxidation data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 4, 6c & S4 in the paper and its supplementary information. en public cc_by

CO oxidation_paper.zip

data 16306 6 57519 document 16306 XPS_CeOx_Data.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet c0542649775928aeaa8559cdb4ef5d8d MD5 768254 2022-12-02 14:54:25 https://researchdata.bath.ac.uk/1190/5/XPS_CeOx_Data.xlsx 1190 5 5 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other XPS data from mesoporous cerium oxide. One of the worksheets provides the key to the data. Data corresponds to Figure S5 in the paper's supplementary information. en public cc_by

XPS_CeOx_Data.xlsx

data 16307 4 54697 document 16307 SEM_EDX_paper.zip application/zip 112a3b85d3b87418e89cdae919dd9988 MD5 11730565 2022-08-22 17:38:33 https://researchdata.bath.ac.uk/1190/6/SEM_EDX_paper.zip 1190 6 6 application/zip other SEM EDX data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. en public cc_by

SEM_EDX_paper.zip

data 16308 4 54714 document 16308 TPR data_paper.zip application/zip 874cddeac8f0fe6151ce129659e85ba9 MD5 157543 2022-08-23 09:37:47 https://researchdata.bath.ac.uk/1190/7/TPR%20data_paper.zip 1190 7 7 application/zip other TPR data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. en public cc_by

TPR data_paper.zip

data archive 10969 disk0/00/00/11/90 2022-12-22 13:27:23 2024-07-15 11:00:04 2022-12-22 13:27:23 data_collection show Manasi Iva im554@bath.ac.uk 0000-0002-3161-4350 University of Bath TRUE Castaing Rémi R.Castaing@bath.ac.uk University of Bath FALSE Edler Karen K.Edler@bath.ac.uk 0000-0001-5822-0127 University of Bath FALSE Andalibi Mohammad 0000-0002-7978-1596 University of Cambridge FALSE CA0010 CG0010 dept_chem Each ZIP file contains an MS Excel spreadsheet that provides details of the samples identified by number in the data file names. In "SAXS_paper.zip", the .dat files are comma-separated value (CSV) plain text files. In "XRD paper.zip", the .raw files are STOE RAW Powder X-ray diffraction files (from a STOE STADI P instrument) and the .xyd files are fixed-width field plain text files. This dataset relates to a novel, low temperature and green method for atom-efficient solvothermal synthesis of crystalline, micelle templated cerium IV oxide (ceria) from a type IV deep eutectic solvent (DES) comprising a hydrated cerium containing metal salt, cerium(iii) nitrate hexahydrate (Ce(NO₃)₃·6H₂O), and a hydrogen bond donor, urea, in a molar ratio of 1:3.5. We have used high concentration (20% w/w) solutions of C-12 and C-16 alkyl chain length cationic surfactants (CₙTAB and CₙTANO₃) and C-16 alkyl chain length non-ionic surfactant BrijC₁₀ in the DES to alter the porosity of the cerium oxide produced. The characterisation of the cerium oxide has been carried out using scanning and transmission electron microscopy (SEM/TEM), N₂ sorption, Small Angle X-ray Scattering (SAXS) and temperature programmed reduction (TPR) to understand and quantify the nature of the crystallinity, morphology and porosity along with CO oxidation for the catalytic activity of the material. Included in the dataset are the X-ray diffraction (XRD), SAXS, N₂ sorption, SEM Energy Dispersive X-Ray Analysis (EDX), X-ray photoelectron (XPS) and CO oxidation characterization data for these materials. 2022-08-08 University of Bath public RightsHolder University of Bath Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/S020772/1 Enabling industrial deployment of deep eutectic solvents through manufacturing tools Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/S021019/1 Enabling industrial deployment of deep eutectic solvents through manufacturing tools Full details of the methodology can be found in the Materials and Methods section of the associated paper. https://doi.org/10.1039/D2TA05693C en 1 10.15125/BATH-01190 https://doi.org/10.1039/D2TA05693C pub open Dataset