This dataset contains nuclear magnetic resonance (NMR) raw data for all novel compounds reported in the associated publication, "Synthesis of N-alkoxycarbonyl pyrroles from O-substituted carbamates – A synthetically enabling pyrrole protection strategy". The NMR files are provided as FID (Free Induction Decay) files, the standard format for NMR raw data. There are multiple software packages that can read this data, including but not limited to MestreNova, TopSpinACD/Labs NMR Workbook suite, ACD/Labs Spectrus JS.