1368 37 17730 2 65418 document 17730 3D PhotoFoam Dataset.zip application/zip 9f130050e734221fb015bf476c3f23a3 MD5 9704608 2024-01-26 14:55:54 https://researchdata.bath.ac.uk/1368/1/3D%20PhotoFoam%20Dataset.zip 1368 1 1 application/zip other Raw data files for XRD, HPLC, NMR, Rheometry, RAMAN and TGA. en public cc_by

3D PhotoFoam Dataset.zip

data archive 10236 disk0/00/00/13/68 2024-04-17 08:17:28 2024-07-15 11:00:14 2024-04-17 08:17:28 data_collection show Warren Zachary zw799@bath.ac.uk 0000-0001-9455-3375 University of Bath TRUE Tasso Guaraldo Thais T.Tasso.Guaraldo@bath.ac.uk 0000-0002-7308-4909 Coventry University FALSE Barisic Ivan ib503@bath.ac.uk 0009-0003-9237-5239 University of Bath FALSE Zoumpouli Liana gz305@bath.ac.uk 0000-0001-5501-2656 University of Bath FALSE Wenk Jannis J.H.Wenk@bath.ac.uk 0000-0001-9182-0407 University of Bath FALSE Mattia Davide D.Mattia@bath.ac.uk 0000-0002-7679-4105 University of Bath FALSE CA0010 EG0040 EG0050 GE0030 GM0100 KM0070 dept_chem_eng Photocatalysis, Micropollutant, 3D Printing, Titanium Dioxide, Pharmaceuticals Raw data files for X-ray diffraction (XRD), high-performance liquid chromatography (HPLC), Nuclear Magnetic Resonance (NMR), Rheometry and Thermogravimetric analysis (TGA) associated with the paper "Mixed-Phase Titania foams via 3D-Printing for Pharmaceutical Degradation." XRD contains raw data of XRD spectra used to analyse crystallinity and crystal phase of TiO2 samples. HPLC contains the raw data used to produce degradation profiles of carbamazepine when exposed to the photocatalyst. NMR contains the maestranova files used to monitor the reaction and synthesis of photoresist. Rheometry contains the data used to analyse the viscosity of the resins before and after modifications. RAMAN contains the raw data used to analyse the crystal phases of the samples. TGA contains the raw data used to assess minimum required temperature for sintering and conversion to TiO2. 2024-04-03 University of Bath public RightsHolder University of Bath Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/P031382/1 Fellowship - Photocatalytic Anodic Membranes for Micropollutant Removal wirc XRD — Sampling between 2θ of 20–90 with Cu K alpha X-rays. HPLC — Degradation experiments used 1 mL samples taken every 15 or 30 minutes. Analysis was performed on a Thermo Scientific Ultimate 3000 liquid chromatograph with a UV detector. CBZ analysis used a Thermo Scientific Acclaim 120 C18 column (3.0 × 75.0 mm, particle size 3.0 µm) and a Thermo Scientific Acclaim 120 C18 guard column (R) 120 C18 (3.0 × 10.0 mm, particle size 5.0 µm). The mobile phase was made up using 5.0 mM phosphoric acid and acetonitrile 70:30 (v:v) with a flow rate of 0.8 mL min⁻¹, injection volume of 20 µL and detection wavelength of 285 nm. NMR analysis of the titania photoresist was conducted as the orange product (Ti(IV) acrylate) and acrylic acid precursor were dissolved in deuterated chloroform (CDCl3) for analysis on a 400 MHz Bruker Avance III NMR spectrometer Thermogravimetric analysis was conducted using a Setsys Evolution TGA 16/18 by Setaram, with the acquisition program Calisto. 20 mg of sample was loaded in an open alumina crucible. Prior to the analysis, samples were degassed at 90 °C for 1h and 350 °C for 8h at 10 °C min-1 to remove water from the surface. Analysis was performed under air or argon atmosphere (20 mL min-1) and heated up to 800 °C for 1h at a rate of 10 °C min-1. The rheometry of all resins used in this study was conducted on a Brookfield HADV-III Ultra-Viscometer with a CP52 cone spindle. Raman spectra used in this work were collected using a Renishaw InVia Confocal Raman microscope, excitation laser wavelength 532 nm, 100% laser power at 74 mW on the sample with 2.6 s exposure time, and a diffraction grating of size 1800 I/ mm with slit opening of 65 mm. Detector used was a 1040 × 256 pixel CCD camera. NMR data requires use of MaestReNova 15 (Mnova 15.0.0) Download available using https://mestrelab.com/download/mnova/ 2023-01-31 2023-07-31 en 1 10.15125/BATH-01368 https://doi.org/10.1039/D4TA00869C pub open Dataset