1387 251 17843 6 66205 document 17843 Fig8_Dofr_CaAS2649_part1.agr text/plain a396014e04cc16672fefacced55087d6 MD5 315451 2024-04-08 12:58:21 https://researchdata.bath.ac.uk/1387/7/Fig8_Dofr_CaAS2649_part1.agr 1387 7 7 text/plain other Figure 8 shows the pressure dependence of several D'(r) functions for glassy CaAS_26_49. en public cc_by

Fig8_Dofr_CaAS2649_part1.agr

data 17844 5 66207 document 17844 Fig9_Dofr_CaAS_recovered.agr text/plain dad44ea86dac018542a503b5672c5a32 MD5 316047 2024-04-08 12:59:24 https://researchdata.bath.ac.uk/1387/8/Fig9_Dofr_CaAS_recovered.agr 1387 8 8 text/plain other Figure 9 shows the fitted D'(r) functions for (a) and (b) glassy CaAS_19_61 and (c) glassy CaAS_26_49 recovered from high pressure conditions en public cc_by

Fig9_Dofr_CaAS_recovered.agr

data 17845 4 66217 document 17845 Fig1_27Al_NMR.agr text/plain 1c70f50c529b26f4aabf7a874fb664f7 MD5 4099059 2024-04-08 13:01:58 https://researchdata.bath.ac.uk/1387/9/Fig1_27Al_NMR.agr 1387 9 1 text/plain other Figure 1 shows the fitted ^{27}Al MAS NMR spectra for the CaAS_19_61 and CaAS_26_49 glasses recovered from high pressure conditions. en public cc_by

Fig1_27Al_NMR.agr

data 17847 4 66221 document 17847 Fig4_Fofq_CaAS_26_49.agr text/plain 9bd8b63ca3cb70bd525dc1c0dae36dd2 MD5 138234 2024-04-08 13:02:34 https://researchdata.bath.ac.uk/1387/11/Fig4_Fofq_CaAS_26_49.agr 1387 11 3 text/plain other Figure 4 shows the total structure factors F(k) measured using D4c for uncompressed, compressed or recovered CaAS_26_49 glass. en public cc_by

Fig4_Fofq_CaAS_26_49.agr

data 17848 4 66223 document 17848 Fig5_k-space_peak_positions.agr text/plain 87b0975194473475faf8b3a91f639ae4 MD5 34804 2024-04-08 13:02:55 https://researchdata.bath.ac.uk/1387/12/Fig5_k-space_peak_positions.agr 1387 12 4 text/plain other Figure 5 shows the pressure dependence of the FSDP position k_{FSDP} and principal peak position k_{PP} in the measured F(k) functions. en public cc_by

Fig5_k-space_peak_positions.agr

data 17849 5 66225 document 17849 Fig6_EOS.agr text/plain 4e8bb8d139593b3da7a7554c1e8cbedf MD5 65630 2024-04-08 13:03:26 https://researchdata.bath.ac.uk/1387/13/Fig6_EOS.agr 1387 13 5 text/plain other Figure 6 shows the pressure-volume equation of state for calcium aluminosilicates. en public cc_by

Fig6_EOS.agr

data 17850 6 66227 document 17850 Fig7_Dofr_CaAS1961_part1.agr text/plain e2b308034e975bda0b137f8c848667b8 MD5 550655 2024-04-08 13:03:48 https://researchdata.bath.ac.uk/1387/14/Fig7_Dofr_CaAS1961_part1.agr 1387 14 6 text/plain other Figure 7 shows the pressure dependence of several D'(r) functions for glassy CaAS_19_61. en public cc_by

Fig7_Dofr_CaAS1961_part1.agr

data 17851 3 66263 document 17851 Fig10_r-space_data.agr text/plain 317a2fd40995c6bb2a9c1ac4f239eef9 MD5 60773 2024-04-08 13:05:40 https://researchdata.bath.ac.uk/1387/15/Fig10_r-space_data.agr 1387 15 15 text/plain other Figure 10 shows the pressure dependence of (a) the A-O bond distances (A = Si or Al) and (b) the Al-O coordination number. en public cc_by

Fig10_r-space_data.agr

data 17852 2 66265 document 17852 Fig11_AlO_CN_vs_pmax.agr text/plain 5ab638afa6f499070f980eb69369e31f MD5 17962 2024-04-08 13:06:26 https://researchdata.bath.ac.uk/1387/16/Fig11_AlO_CN_vs_pmax.agr 1387 16 16 text/plain other Figure 11 shows the dependence of the Al-O coordination number on the maximum applied pressure p_{max} in cold-compression experiments on glassy CaAS_26_49, CaAS_19_61, pyrope and MgAS_37.5_50. en public cc_by

Fig11_AlO_CN_vs_pmax.agr

data 17853 2 66267 document 17853 Fig12_O-packing_v3.agr text/plain 8bcb97933004d932dabf8afd5fe8851a MD5 110455 2024-04-08 13:07:58 https://researchdata.bath.ac.uk/1387/17/Fig12_O-packing_v3.agr 1387 17 17 text/plain other Figure 12 shows the dependence of the A-O coordination number for network-forming motifs (A = B, Ge, Si, or Si and Al) on the oxygen packing fraction for several glassy and liquid network-forming systems under pressure. en public cc_by

Fig12_O-packing_v3.agr

data 17857 3 66275 document 17857 Fig16a_NBO_expt_vs_model_v4.agr text/plain b206867049e92feba79875e938c33e67 MD5 24492 2024-04-08 13:14:47 https://researchdata.bath.ac.uk/1387/21/Fig16a_NBO_expt_vs_model_v4.agr 1387 21 21 text/plain other Figure 16(a) shows the measured versus calculated values of f_{NBO} for silicate and aluminosilicate glasses. The network formers were presumed to be all the Si(j) species and, in the case of the aluminosilicates, all the Al(j) species. en public cc_by

Fig16a_NBO_expt_vs_model_v4.agr

data 17858 3 66277 document 17858 Fig16b_NBO_expt_vs_model_Al4+Al5.agr text/plain b6e7ec4039dd0a68309a6b4f56f70f29 MD5 24489 2024-04-08 13:18:31 https://researchdata.bath.ac.uk/1387/22/Fig16b_NBO_expt_vs_model_Al4%2BAl5.agr 1387 22 22 text/plain other Figure 16(b) shows the measured versus calculated values of f_{NBO} for silicate and aluminosilicate glasses. The network formers were presumed to be all the Si(j) species and, in the case of the aluminosilicates, only the Al(IV) and Al(V) species. en public cc_by

Fig16b_NBO_expt_vs_model_Al4+Al5.agr

data 17859 2 66303 document 17859 Fig17a_fNBO_vs_density_all_Al.agr text/plain 5035f20e128bfc66f9ea8f6fd655fe09 MD5 35635 2024-04-08 14:10:18 https://researchdata.bath.ac.uk/1387/23/Fig17a_fNBO_vs_density_all_Al.agr 1387 23 23 text/plain other Figure 17(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

Fig17a_fNBO_vs_density_all_Al.agr

data 17860 2 66305 document 17860 Fig17b_fNBO_vs_Al-O_CN_all_Al.agr text/plain 1de1d65d1524ead23f9708e4147bd44b MD5 36205 2024-04-08 14:12:41 https://researchdata.bath.ac.uk/1387/24/Fig17b_fNBO_vs_Al-O_CN_all_Al.agr 1387 24 24 text/plain other Figure 17(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

Fig17b_fNBO_vs_Al-O_CN_all_Al.agr

data 17865 2 66315 document 17865 Fig20a_fNBO_vs_density_depolymerised_Al4+Al5.agr text/plain 7e9c0171c9a994d3cb5be3f36f843b5d MD5 35909 2024-04-08 14:23:20 https://researchdata.bath.ac.uk/1387/29/Fig20a_fNBO_vs_density_depolymerised_Al4%2BAl5.agr 1387 29 29 text/plain other Figure 20(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

Fig20a_fNBO_vs_density_depolymerised_Al4+Al5.agr

data 17866 2 66317 document 17866 Fig20b_fNBO_vs_Al-O_CN_depolymerised_Al4+Al5.agr text/plain 9b41a468badf28f1c3e37399c9a1ba00 MD5 35809 2024-04-08 14:24:36 https://researchdata.bath.ac.uk/1387/30/Fig20b_fNBO_vs_Al-O_CN_depolymerised_Al4%2BAl5.agr 1387 30 30 text/plain other Figure 20(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

Fig20b_fNBO_vs_Al-O_CN_depolymerised_Al4+Al5.agr

data 17867 2 66319 document 17867 Fig21_speciation_Drewitt_v3.agr text/plain e114899e28cfa549a16f6ed35f0fe758 MD5 56420 2024-04-08 14:28:16 https://researchdata.bath.ac.uk/1387/31/Fig21_speciation_Drewitt_v3.agr 1387 31 31 text/plain other Figure 21 shows the pressure dependence of the fractions of (a) Si(j) (j = IV, V or VI), (b) Al(j) (j = IV, V or VI), and (c) O-(Al,Si)_i (i = 1, 2, 3 or 4) species found from molecular dynamics simulations of hot-compressed CaAS_25_50 glass at 27 Celsius. en public cc_by

Fig21_speciation_Drewitt_v3.agr

data 17869 2 66334 document 17869 FigS1_27Al_NMR.agr text/plain bed8f485b678f12dba92063e51499c14 MD5 3242297 2024-04-08 14:34:04 https://researchdata.bath.ac.uk/1387/33/FigS1_27Al_NMR.agr 1387 33 33 text/plain other Figure S1 shows the fitted ^{27}Al MAS NMR spectra for the uncompressed CaAS_19_61 and CaAS_26_49 glasses. en public cc_by

FigS1_27Al_NMR.agr

data 17870 3 66336 document 17870 FigS3_Dofr_CaAS1961_part2.agr text/plain ba345109edcb3cd4772fc31be685179c MD5 522546 2024-04-08 14:35:03 https://researchdata.bath.ac.uk/1387/34/FigS3_Dofr_CaAS1961_part2.agr 1387 34 34 text/plain other Figure S3 shows the pressure dependence of several D'(r) functions for glassy CaAS_19_61. en public cc_by

FigS3_Dofr_CaAS1961_part2.agr

data 17871 2 66342 document 17871 FigS4_Dofr_CaAS2649_part2.agr text/plain 7f92d564c0eab9d78e442400385f348c MD5 315404 2024-04-08 14:42:54 https://researchdata.bath.ac.uk/1387/35/FigS4_Dofr_CaAS2649_part2.agr 1387 35 35 text/plain other Figure S4 shows the pressure dependence of several D'(r) functions for glassy CaAS_26_49. en public cc_by

FigS4_Dofr_CaAS2649_part2.agr

data 17872 2 66344 document 17872 FigS5a_fNBO_vs_density_depolymerised_Al4.agr text/plain 614250d0d2e2e2ce9927718001e59a42 MD5 38206 2024-04-08 14:43:57 https://researchdata.bath.ac.uk/1387/36/FigS5a_fNBO_vs_density_depolymerised_Al4.agr 1387 36 36 text/plain other Figure S5(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS5a_fNBO_vs_density_depolymerised_Al4.agr

data 17873 2 66346 document 17873 FigS5b_fNBO_vs_Al-O_CN_depolymerised_Al4.agr text/plain 8f82f6f6d44c267c2801dabf10808a31 MD5 35753 2024-04-08 14:45:27 https://researchdata.bath.ac.uk/1387/37/FigS5b_fNBO_vs_Al-O_CN_depolymerised_Al4.agr 1387 37 37 text/plain other Figure S5(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS5b_fNBO_vs_Al-O_CN_depolymerised_Al4.agr

data 17876 2 66352 document 17876 FigS7a_NBO_per_T_vs_density_depolymerised_Al4.agr text/plain 0c3019a3d0ab58c7e4fcd9fa19d14098 MD5 35684 2024-04-08 14:48:16 https://researchdata.bath.ac.uk/1387/40/FigS7a_NBO_per_T_vs_density_depolymerised_Al4.agr 1387 40 40 text/plain other Figure S7(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS7a_NBO_per_T_vs_density_depolymerised_Al4.agr

data 17877 2 66354 document 17877 FigS7b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4.agr text/plain 4f4600a3d0705e23d0909e3734c1d5ec MD5 33907 2024-04-08 14:50:50 https://researchdata.bath.ac.uk/1387/41/FigS7b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4.agr 1387 41 41 text/plain other Figure S7(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS7b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4.agr

data 17880 2 66360 document 17880 FigS9a_NBO_per_T_vs_density_all_Al.agr text/plain f11d7999062f688bf0db8c14aac5bcbb MD5 34382 2024-04-08 14:54:53 https://researchdata.bath.ac.uk/1387/44/FigS9a_NBO_per_T_vs_density_all_Al.agr 1387 44 44 text/plain other Figure S9(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

FigS9a_NBO_per_T_vs_density_all_Al.agr

data 17881 2 66362 document 17881 FigS9b_NBO_per_T_vs_Al-O_CN_all_Al.agr text/plain 928b4b36053d6413f95a5eebf57b2713 MD5 35333 2024-04-08 14:56:48 https://researchdata.bath.ac.uk/1387/45/FigS9b_NBO_per_T_vs_Al-O_CN_all_Al.agr 1387 45 45 text/plain other Figure S9(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

FigS9b_NBO_per_T_vs_Al-O_CN_all_Al.agr

data 17886 2 66372 document 17886 FigS12a_NBO_per_T_vs_density_depolymerised_Al4+Al5.jpg image/jpeg 952f37167f0a0aeb7f29383037883fa4 MD5 743775 2024-04-08 15:02:22 https://researchdata.bath.ac.uk/1387/50/FigS12a_NBO_per_T_vs_density_depolymerised_Al4%2BAl5.jpg 1387 50 50 image/jpeg other Figure S12(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

FigS12a_NBO_per_T_vs_density_depolymerised_Al4+Al5.jpg

data 17887 2 66374 document 17887 FigS12b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4+Al5.agr text/plain 48ed72a1d0997238cc456371abb3d477 MD5 35450 2024-04-08 15:03:50 https://researchdata.bath.ac.uk/1387/51/FigS12b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4%2BAl5.agr 1387 51 51 text/plain other Figure S12(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the depolymerized glasses with f_{NBO} ~0.22-0.24 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

FigS12b_NBO_per_T_vs_Al-O_CN_depolymerised_Al4+Al5.agr

data 17889 2 66401 document 17889 lightbox.jpg image/png 667b4bcbbbe7a2a08b35109837a3318f MD5 71794 2024-04-08 15:22:47 https://researchdata.bath.ac.uk/1387/53/lightbox.jpg 1387 53 53 image/png other Thumbnails conversion from other to thumbnail_lightbox en public

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http://eprints.org/relation/isVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/isVolatileVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/islightboxThumbnailVersionOf https://researchdata.bath.ac.uk/id/document/17886 17890 2 66402 document 17890 preview.jpg image/png c6a40547b235870ca276632efa3f06a3 MD5 37490 2024-04-08 15:22:47 https://researchdata.bath.ac.uk/1387/54/preview.jpg 1387 54 54 image/png other Thumbnails conversion from other to thumbnail_preview en public

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http://eprints.org/relation/isVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/isVolatileVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/ispreviewThumbnailVersionOf https://researchdata.bath.ac.uk/id/document/17886 17891 2 66403 document 17891 medium.jpg image/png 79b09efb3462b97c9ec3ea2c2495ef20 MD5 16107 2024-04-08 15:22:47 https://researchdata.bath.ac.uk/1387/55/medium.jpg 1387 55 55 image/png other Thumbnails conversion from other to thumbnail_medium en public

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http://eprints.org/relation/isVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/isVolatileVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/ismediumThumbnailVersionOf https://researchdata.bath.ac.uk/id/document/17886 17892 2 66404 document 17892 small.jpg image/png e8e8ae67ac9bda87ad453da644e5eabf MD5 2973 2024-04-08 15:22:48 https://researchdata.bath.ac.uk/1387/56/small.jpg 1387 56 56 image/png other Thumbnails conversion from other to thumbnail_small en public

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http://eprints.org/relation/isVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/isVolatileVersionOf https://researchdata.bath.ac.uk/id/document/17886 http://eprints.org/relation/issmallThumbnailVersionOf https://researchdata.bath.ac.uk/id/document/17886 17988 2 67094 document 17988 Fig3_Fofq_CaAS_19_61_v2.agr text/plain cb84d00cda3e5cd814ad5bd43b7c7771 MD5 270744 2024-05-05 10:02:15 https://researchdata.bath.ac.uk/1387/58/Fig3_Fofq_CaAS_19_61_v2.agr 1387 58 58 text/plain other Figure 3 shows the total structure factors F(k) measured using D4c for uncompressed, compressed or recovered CaAS_19_61 glass. en public cc_by

Fig3_Fofq_CaAS_19_61_v2.agr

data 18066 2 68785 document 18066 Fig13_Al-CN_vs_density_v8.agr text/plain e094ed772fee1f3f0299cad6814b3a78 MD5 146762 2024-06-15 15:07:14 https://researchdata.bath.ac.uk/1387/59/Fig13_Al-CN_vs_density_v8.agr 1387 59 59 text/plain other Figure 13 shows Reduced density dependence of the Al-O coordination number for (a) calcium aluminosilicate glasses along or close to the tectosilicate tie-line and (b) a variety of other aluminosilicate glasses. en public cc_by

Fig13_Al-CN_vs_density_v8.agr

data 18067 2 68787 document 18067 Fig14_Al_speciation_vs_density_27Al_NMR_v2.agr text/plain fca9a5610a4c9fba93ef5b08736ac9e4 MD5 159734 2024-06-15 15:07:56 https://researchdata.bath.ac.uk/1387/60/Fig14_Al_speciation_vs_density_27Al_NMR_v2.agr 1387 60 60 text/plain other Figure 14 shows the reduced density dependence of the aluminum speciation f_{Al(j)} found from ^{27}Al MAS NMR experiments on the uncompressed or recovered glasses of Fig. 13. en public cc_by

Fig14_Al_speciation_vs_density_27Al_NMR_v2.agr

data 18068 2 68789 document 18068 Fig15_Al-O_CN_vs_density_v2.agr text/plain 5d1de1fcab72c390231a5977803b130e MD5 300920 2024-06-15 15:08:30 https://researchdata.bath.ac.uk/1387/61/Fig15_Al-O_CN_vs_density_v2.agr 1387 61 61 text/plain other Figure 15 shows the reduced density dependence of the Al-O coordination number n_{Al}^{O} = 4f_{Al(IV)}+5f_{Al(V)}+6f_{Al(VI)} versus its contributions from the four- plus five-coordinated species, 4f_{Al(IV)}+5f_{Al(V)}, and from the six-coordinated species, 6f_{Al(VI)}. en public cc_by

Fig15_Al-O_CN_vs_density_v2.agr

data 18069 2 68791 document 18069 Fig18a_fNBO_vs_density_no-initial_NBO_all_Al_v3.agr text/plain fd3acf2d455a5f3d3c42fcdfd529875a MD5 23258 2024-06-15 15:09:26 https://researchdata.bath.ac.uk/1387/62/Fig18a_fNBO_vs_density_no-initial_NBO_all_Al_v3.agr 1387 62 62 text/plain other Figure 18(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

Fig18a_fNBO_vs_density_no-initial_NBO_all_Al_v3.agr

data 18070 2 68793 document 18070 Fig18b_fNBO_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr text/plain 12b37c61c13375c7e6226bf664a24dbe MD5 26623 2024-06-15 15:10:06 https://researchdata.bath.ac.uk/1387/63/Fig18b_fNBO_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr 1387 63 63 text/plain other Figure 18(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

Fig18b_fNBO_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr

data 18071 2 68795 document 18071 Fig19a_fNBO_vs_density_no-initial_NBO_Al4+Al5_v2.agr text/plain abb9f02519abb769648ef92b73b50e49 MD5 22687 2024-06-15 15:10:43 https://researchdata.bath.ac.uk/1387/64/Fig19a_fNBO_vs_density_no-initial_NBO_Al4%2BAl5_v2.agr 1387 64 64 text/plain other Figure 19(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

Fig19a_fNBO_vs_density_no-initial_NBO_Al4+Al5_v2.agr

data 18072 2 68797 document 18072 Fig19b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4+Al5_v2.agr text/plain 8f3002468fe4df6356cdb267ee95107b MD5 42992 2024-06-15 15:11:16 https://researchdata.bath.ac.uk/1387/65/Fig19b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4%2BAl5_v2.agr 1387 65 65 text/plain other Figure 19(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

Fig19b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4+Al5_v2.agr

data 18074 2 68809 document 18074 FigS6a_fNBO_vs_density_no-initial_NBO_Al4_v2.agr text/plain 1c321b5e70085a5cd1edde595cfbeeaf MD5 23243 2024-06-15 15:22:53 https://researchdata.bath.ac.uk/1387/67/FigS6a_fNBO_vs_density_no-initial_NBO_Al4_v2.agr 1387 67 67 text/plain other Figure S6(a) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS6a_fNBO_vs_density_no-initial_NBO_Al4_v2.agr

data 18075 2 68811 document 18075 FigS6b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4_v2.agr text/plain 8196b50343d8be5edd73ae1d7d1fb55e MD5 26513 2024-06-15 15:23:42 https://researchdata.bath.ac.uk/1387/68/FigS6b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4_v2.agr 1387 68 68 text/plain other Figure S6(b) shows the dependence of the fraction of non-bridging oxygen atoms f_{NBO} on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS6b_fNBO_vs_Al-O_CN_no-initial_NBO_Al4_v2.agr

data 18076 2 68813 document 18076 FigS8a_NBO_per_T_vs_density_polymerised_Al4_v3.agr text/plain 4a852596a735bf2a390003bb5b89f5d5 MD5 23229 2024-06-15 15:24:35 https://researchdata.bath.ac.uk/1387/69/FigS8a_NBO_per_T_vs_density_polymerised_Al4_v3.agr 1387 69 69 text/plain other Figure S8(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS8a_NBO_per_T_vs_density_polymerised_Al4_v3.agr

data 18077 2 68815 document 18077 FigS8b_NBO_per_T_vs_Al-O_CN_polymerised_Al4_v3.agr text/plain 7fc0fdf875cf98298a6ec5f37fc5811c MD5 26552 2024-06-15 15:25:11 https://researchdata.bath.ac.uk/1387/70/FigS8b_NBO_per_T_vs_Al-O_CN_polymerised_Al4_v3.agr 1387 70 70 text/plain other Figure S8(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV) and Al(IV) species contribute towards the network. en public cc_by

FigS8b_NBO_per_T_vs_Al-O_CN_polymerised_Al4_v3.agr

data 18078 2 68817 document 18078 FigS10a_NBO_per_T_vs_density_no-initial_NBO_all_Al_v4.agr text/plain 4d5e6754b3d312cc7050ef0a059333a3 MD5 23355 2024-06-15 15:26:01 https://researchdata.bath.ac.uk/1387/71/FigS10a_NBO_per_T_vs_density_no-initial_NBO_all_Al_v4.agr 1387 71 71 text/plain other Figure S10(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

FigS10a_NBO_per_T_vs_density_no-initial_NBO_all_Al_v4.agr

data 18079 2 68819 document 18079 FigS10b_NBO_per_T_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr text/plain bc18923e10cae5984ffc35f56802b038 MD5 26586 2024-06-15 15:26:35 https://researchdata.bath.ac.uk/1387/72/FigS10b_NBO_per_T_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr 1387 72 72 text/plain other Figure S10(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and all the Si(IV) and aluminum species contribute towards the network. en public cc_by

FigS10b_NBO_per_T_vs_Al-O_CN_no-initial_NBO_all_Al_v3.agr

data 18080 2 68821 document 18080 FigS11a_NBO_per_T_vs_density_polymerised_Al4+Al5_v2.agr text/plain 74bb032cc36bf77a5100f1ac93e6555d MD5 22775 2024-06-15 15:27:34 https://researchdata.bath.ac.uk/1387/73/FigS11a_NBO_per_T_vs_density_polymerised_Al4%2BAl5_v2.agr 1387 73 73 text/plain other Figure S11(a) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the reduced density rho^prime for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

FigS11a_NBO_per_T_vs_density_polymerised_Al4+Al5_v2.agr

data 18081 2 68823 document 18081 FigS11b_NBO_per_T_vs_Al-O_CN_polymerised_Al4+Al5_v2.agr text/plain a6861fffd07e11ee4f96eeb3bac2e0d1 MD5 26068 2024-06-15 15:28:14 https://researchdata.bath.ac.uk/1387/74/FigS11b_NBO_per_T_vs_Al-O_CN_polymerised_Al4%2BAl5_v2.agr 1387 74 74 text/plain other Figure S11(b) shows the dependence of the number of non-bridging oxygen atoms per tetrahedron N_{NBO}/N_T on the Al-O coordination number for the tectosilicate glasses with f_{NBO} ~0 at rho^prime = 1. The fraction of NBO atoms was calculated by assuming that f_{Si(IV)} = 1 and only the Si(IV), Al(IV) and Al(V) species contribute towards the network. en public cc_by

FigS11b_NBO_per_T_vs_Al-O_CN_polymerised_Al4+Al5_v2.agr

data 18082 2 68851 document 18082 Fig22_O2_vs_O3_density_v5.agr text/plain 1f5fc4e842bb70b930af6ce7672cda25 MD5 123380 2024-06-16 10:21:11 https://researchdata.bath.ac.uk/1387/75/Fig22_O2_vs_O3_density_v5.agr 1387 75 75 text/plain other Figure 22 shows the reduced density dependence of the fractions of O(j) (j = I, II, III or IV) species for (a) glassy CaAS_25_50 at 27 Celsius, (b) liquid CaAS_25_50 at 2,227 Celsius, (c) glassy CaAS_19_61 and CaAS_26_49 at 25 Celsius, and (d) several recovered tectosilicate glasses. en public cc_by

Fig22_O2_vs_O3_density_v5.agr

data 18083 2 68853 document 18083 FigS13_O2_vs_O3_v3.agr text/plain 931730a3cb814a6b94bbde264606dff0 MD5 75839 2024-06-16 10:21:57 https://researchdata.bath.ac.uk/1387/76/FigS13_O2_vs_O3_v3.agr 1387 76 76 text/plain other Figure S13 shows the pressure dependence of the fractions of O(j) (j = I, II, III or IV) species for (a) glassy CaAS_25_50 at 27 Celsius, (b) liquid CaAS_25_50 at 2,227 Celsius, and (c) glassy CaAS_19_61 and CaAS_26_49 at 25 Celsius. en public cc_by

FigS13_O2_vs_O3_v3.agr

data archive 479 disk0/00/00/13/87 2024-08-06 09:56:59 2026-01-10 05:54:12 2024-08-06 09:56:59 data_collection show Salmon Philip P.S.Salmon@bath.ac.uk 0000-0001-8671-1011 University of Bath TRUE Zeidler Anita A.Zeidler@bath.ac.uk 0000-0001-6501-8525 University of Bath FALSE WorkPackageLeader Youngman Randall E youngmanre@corning.com 0000-0002-6647-9865 Corning BS0050 CM0040 EM0050 EM0060 EV0100 GE0030 dept_physics Glass structure, pressure, neutron diffraction, solid-state NMR, densified glass, oxygen packing, network polymerization The files are labelled according to the corresponding figure numbers. The units for each axis are identified on the plots. Data sets used to prepare Figures 1, 3-22, S1 and S3-S13 in the Journal of Chemical Physics article entitled "Transformations to the aluminum coordination environment and network polymerization in amorphous aluminosilicates under pressure." The data sets describe the structure of amorphous aluminosilicates under, or recovered from, high-pressure conditions. They were obtained by using in situ high-pressure neutron diffraction and solid-state 27Al nuclear magnetic resonance (NMR) spectrocopy. The results are discussed by reference to those obtained from in situ high-pressure x-ray diffraction and solid-state 17O, 27Al, 29Si NMR experiments. 2024-08-06 University of Bath public RightsHolder University of Bath Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/L015544/1 EPSRC Centre for Doctoral Training in Condensed Matter Physics Royal Society https://doi.org/10.13039/501100000288 DH140152 Dorothy Hodgkin Research Fellowship - Rational Design of Glassy Materials with Technological Applications Diamond Light Source https://doi.org/10.13039/100011889 STU0173 ISIS/Diamond Facility Development Studentship ISIS Neutron and Muon Source (The ISIS Neutron and Muon Source) https://doi.org/10.13039/501100021200 STU0173 ISIS/Diamond Facility Development Studentship cent_nan The data sets were collected using the methods described in the published paper. The data sets were analysed using the methods described in the published paper. The figures were prepared using QtGrace (https://sourceforge.net/projects/qtgrace/). The data set corresponding to a plotted curve within an QtGrace file can be identified by clicking on that curve. 2018-05-09 2024-06-14 en 1 10.15125/BATH-01387 https://doi.org/10.1063/5.0218574 pub open Dataset