This document contains complete research data and supporting information in paper "Physical Origin of Temperature Induced Activation Energy Switching in Electrically Conductive Cement" that has been published in the journal of Advanced Science.

The research data contains complete results of thermodynamic modelling, microstructural characterisation, and mathematical deductive process for automation algorithm development. 

The supporting information contains the associated methods and methodologies to produce the research data.

Contents in supporting information include:
SI – 1. Materials and mix design
SI – 2. Fabrication process
SI – 3. Thermal cycle configurations
SI – 4. Electrochemical impedance spectroscopy (EIS)
SI – 5. Variation in moisture content during thermal cycle
SI – 6. Chemical equilibria of simulated pore solution
SI – 7. Thermodynamic modelling
SI – 8. Calculation of electrical parameters
SI – 9. Calculation of activation energies	24
SI – 10. Meyer–Neldel Rule (MNR) validation
SI – 11. Microstructural characterization
SI – 12. Development of electrical conductivity through curing age
SI – 13. Effect of temperature and fibre content on impedance behaviours
SI – 14. Thermally induced alteration in the architecture of conduction pathways
SI – 15. Determination on ionic and electronic conductivity percentages
SI – 16. Solving process of environmental susceptibility χ for automation

Contents in research data include:
1. Complete data of impedance response of all the samples through curing ages
2. Complete data of thermodynamic modelling outputs