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        <formatdesc>This file contains complete research data and supporting information in paper &quot;Physical Origin of Temperature Induced Activation Energy Switching in Electrically Conductive Cement&quot; that has been published in the journal of Advanced Science.</formatdesc>
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        <name>
          <family>Zhang</family>
          <given>Jiacheng</given>
        </name>
        <id>jz2031@bath.ac.uk</id>
        <orcid>0000-0001-5380-0050</orcid>
        <affiliation>University of Bath</affiliation>
        <contact>TRUE</contact>
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        <name>
          <family>Heath</family>
          <given>Andrew</given>
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        <id>A.Heath@bath.ac.uk</id>
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        <affiliation>University of Bath</affiliation>
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          <given>Richard</given>
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        <affiliation>University of Bath</affiliation>
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        <name>
          <family>Ke</family>
          <given>Xinyuan</given>
        </name>
        <id>X.Ke@bath.ac.uk</id>
        <orcid>0000-0002-1239-6861</orcid>
        <affiliation>University of Bath; Commonwealth Scholarship Commission in the UK</affiliation>
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          <family>Paine</family>
          <given>Kevin</given>
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        <affiliation>University of Bath</affiliation>
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    <title>Data set for &quot;Physical Origin of Temperature Induced Activation Energy Switching in Electrically Conductive Cement&quot;</title>
    <subjects>
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      <item>CP0070</item>
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    <divisions>
      <item>dept_civ_eng</item>
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    <keywords>Electrically conductive cement, Temperature, Carbon fibre, Activation energy switching, Non-Arrhenius behaviour, Thermodynamic modelling, Meyer-Neldel Rule, Pore solution chemistry, SEM-BSE-EDX, Mercury intrusion porosimetry (MIP), Electrochemical impedance spectroscopy (EIS), Fractal dimension</keywords>
    <abstract>This document contains complete research data and supporting information in paper &quot;Physical Origin of Temperature Induced Activation Energy Switching in Electrically Conductive Cement&quot; that has been published in the journal of Advanced Science.

The research data contains complete results of thermodynamic modelling, microstructural characterisation, and mathematical deductive process for automation algorithm development. 

The supporting information contains the associated methods and methodologies to produce the research data.

Contents in supporting information include:
SI – 1. Materials and mix design
SI – 2. Fabrication process
SI – 3. Thermal cycle configurations
SI – 4. Electrochemical impedance spectroscopy (EIS)
SI – 5. Variation in moisture content during thermal cycle
SI – 6. Chemical equilibria of simulated pore solution
SI – 7. Thermodynamic modelling
SI – 8. Calculation of electrical parameters
SI – 9. Calculation of activation energies	24
SI – 10. Meyer–Neldel Rule (MNR) validation
SI – 11. Microstructural characterization
SI – 12. Development of electrical conductivity through curing age
SI – 13. Effect of temperature and fibre content on impedance behaviours
SI – 14. Thermally induced alteration in the architecture of conduction pathways
SI – 15. Determination on ionic and electronic conductivity percentages
SI – 16. Solving process of environmental susceptibility χ for automation

Contents in research data include:
1. Complete data of impedance response of all the samples through curing ages
2. Complete data of thermodynamic modelling outputs</abstract>
    <date>2025-11-17</date>
    <publisher>University of Bath</publisher>
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        <corpname>University of Shanghai for Science and Technology</corpname>
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        <corpname>University of Shanghai for Science and Technology</corpname>
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        <funder_name>Engineering and Physical Sciences Research Council</funder_name>
        <funder_id>https://doi.org/10.13039/501100000266</funder_id>
        <grant_id>EP/P02081X/1</grant_id>
        <project_name>RM4L - Resilient Materials for Life</project_name>
      </item>
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        <funder_name>National Natural Science Foundation of China</funder_name>
        <funder_id>https://doi.org/10.13039/501100001809</funder_id>
        <grant_id>22476131</grant_id>
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        <funder_name>China Postdoctoral Science Foundation</funder_name>
        <funder_id>https://ror.org/0426zh255</funder_id>
        <grant_id>2024M762092</grant_id>
      </item>
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        <funder_name>Science and Technology Commission of Shanghai Municipality</funder_name>
        <funder_id>https://doi.org/10.13039/501100003399</funder_id>
        <grant_id>24PJA091</grant_id>
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        <funder_name>Engineering and Physical Sciences Research Council</funder_name>
        <funder_id>https://doi.org/10.13039/501100000266</funder_id>
        <grant_id>EP/W010828/1</grant_id>
        <project_name>High-performance carbon-neutral Geopolymer heat Battery for thermochemical energy storage in net-zero buildings</project_name>
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    <collection_method>The data collection method is contained in supporting information.</collection_method>
    <techinfo>The technical details and requirements are contained in supporting information.</techinfo>
    <language>en</language>
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    <doi>10.15125/BATH-01577</doi>
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    <access_arrangements>This document contains the research data and supporting information which is necessary for submission to journal along with manuscript for a comprehensive proof of scientific findings in the paper and for a complete justification of research integrity. 

Most of the data and methods in this document are originally developed by the authors and are developed for the first time in this field of research. To offer necessary protection and respect on the intellectual assets, this document is protected in University of Bath Research Data Archive with a unique DOI.

Access will be granted to bona fide researchers only for non-commercial purposes. Requests will be screened by one of the corresponding authors. Citation is mandatory if referring any original methods in this dataset.</access_arrangements>
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