591 21 10195 3 30021 document 10195 Dataset - Alkali activation behaviour of un-calcined montmorillonite and illite clay minerals.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet e13671df0ccbc0f0b7410e4a0060f280 MD5 14443665 2018-09-09 09:59:30 https://researchdata.bath.ac.uk/591/1/Dataset%20-%20Alkali%20activation%20behaviour%20of%20un-calcined%20montmorillonite%20and%20illite%20clay%20minerals.xlsx 591 1 1 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other en public cc_by

Dataset - Alkali activation behaviour of un-calcined montmorillonite and illite clay minerals.xlsx

data 10222 2 30241 document 10222 Dataset - Alkali activation behaviour of un-calcined montmorillonite and illite clay minerals v2.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 2f84d0d2b987d103562b3b2e18a69851 MD5 19480274 2019-01-25 21:17:07 https://researchdata.bath.ac.uk/591/2/Dataset%20-%20Alkali%20activation%20behaviour%20of%20un-calcined%20montmorillonite%20and%20illite%20clay%20minerals%20v2.xlsx 591 2 2 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other en public cc_by

Dataset - Alkali activation behaviour of un-calcined montmorillonite and illite clay minerals v2.xlsx

data archive 6641 disk0/00/00/05/91 2019-02-07 13:00:09 2024-07-15 10:59:00 2019-02-07 13:00:09 data_collection 549 show Marsh Alastair A.Marsh@bath.ac.uk 0000-0002-5603-4643 University of Bath TRUE Supervisor Heath Andrew A.Heath@bath.ac.uk 0000-0003-0154-0941 University of Bath Supervisor Patureau Pascaline P.M.F.Patureau@bath.ac.uk University of Bath Supervisor Evernden Mark M.Evernden@bath.ac.uk 0000-0003-1121-9844 University of Bath Supervisor Walker Pete P.Walker@bath.ac.uk 0000-0001-9648-3999 University of Bath CP0020 CP0110 GE0030 GE0040 dept_civ_eng alkali activation, geopolymer, montmorillonite, illite, clay Chemical characterisation data describing the precursors and cured products formed when reacting montmorillonite and illite clay precursors with sodium hydroxide solution at Na:Al molar ratios of 0-1.5 and 0-0.75. Version 2 includes additional data for the mass spectrometry results. 2019-02-07 University of Bath public RightsHolder University of Bath Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/L016869/1 EPSRC Centre for Doctoral Training in the Decarbonisation of the Built Environment (DBE) Fig 1; Fig A2 - Atterberg plastic limit measurements were taken over a range of sodium hydroxide solution concentrations, based on BS 1377-2:1990. Fig 2; Fig 3; Fig 4; Fig A1; Fig A3 - Powder X-ray diffraction (PXRD) analysis was done to identify phases with a Bruker D8 Advance instrument using monochromatic CuKalpha1 L3 (λ = 1.540598 Å) X-radiation and a Vantec superspeed detector. A step size of 0.016⁰(2θ) and step duration of 0.3 seconds were used. Fig 7; Fig 8; Fig A5; - Thermogravimetric analysis (TGA) was done to characterise thermal behaviour, using a Setaram Setsys Evolution TGA over a range of 30 to 1000 °C at a heating rate of 10 °C/minute. An air atmosphere was used, with a flow rate of 20 ml/minute. A connected mass spectrometer was used (Pfeiffer Omni) to identify whether evolved gas species contained OH, H2O, CO or CO2. Fig 9; Fig 10 - Magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectra were measured for 27Al and 29Si to characterise coordination states, using a Varian VNMRS in direct excitation. Standards used were 1M aq. Al(NO3)3 for 27Al and tetramethylsilane for 29Si. Spin rates used were 12 kHz for 27Al and 6 kHz for 29Si, and frequencies used were 104.199 kHz for 27Al and 79.435 MHz for 29Si. Sample holders were 4mm width for 27Al and 6mm width for 29Si. Fig 11; Fig A6 - Fourier Transform Infrared Spectroscopy (FTIR) was done to characterise molecular bonding, using a Perkin-Elmer Frontier with a diamond Attenuated Total Reflectance (ATR) head. Spectra were collected over a range of 4000-600 cm-1 using a resolution of 4cm-1 and 5 scans per spectrum. Fig 2; Fig 3; Fig 4; Fig A1; Fig A3 - Patterns were corrected for sample height shift by calibrating to the most intense quartz reflection (101) at 26.6 °(2θ). Fig 3 - Le Bail extractions and Rietveld refinements of the structure were performed using JANA 2006 to extract the background signal. Fig 11; Fig A6 - Corrections were made for ATR and background using Perkin-Elmer Spectrum software. 2015-10-01 2017-10-01 en 2 10.15125/BATH-00591 https://doi.org/10.1016/j.clay.2018.09.011 pub open