Dataset for "Composite hydrogel spheroids based on cellulose nanofibrils and nanofibrous chiral coordination polymer by green synthesis"

905 51 13509 3 41716 document 13509 Fig3B_data_SAXS-WAXS.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 9d7ede51a5298262d5e8108c655b917b MD5 321719 2020-09-09 11:37:30 https://researchdata.bath.ac.uk/905/1/Fig3B_data_SAXS-WAXS.xlsx 905 1 1 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other SAXS and WAXS data for Figure 3B, where combined SAXS and WAXS patterns are presented for pure Cu-Asp as reference (prepared in water) and OCNF dispersions containing L-Asp at the following concentrations: a) 0 mM (control sample), b) 50 mM, c) 75 mM, d) 100 mM and e) 125 mM. C) SEM image of the cross section of an air-dried hydrogel showing bundles of Cu-Asp crystallites. en public cc_by

Fig3B_data_SAXS-WAXS.xlsx

data 13510 4 41718 document 13510 Fig4_data_rheology1.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet d580e918476dbc317d97aa7cd266e2fd MD5 10907 2020-09-09 11:41:02 https://researchdata.bath.ac.uk/905/2/Fig4_data_rheology1.xlsx 905 2 2 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other Rheology data for Figure 4, where G* and tan(delta) are presented as a function of L-Asp concentration in the range 0-150 mM. en public cc_by

Fig4_data_rheology1.xlsx

data 13512 3 41723 document 13512 Fig6B_data_time-lapse-optical-microscopy.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet a920ac9793279e5a1b1ad2d791a98e77 MD5 221394 2020-09-09 11:48:56 https://researchdata.bath.ac.uk/905/3/Fig6B_data_time-lapse-optical-microscopy.xlsx 905 3 3 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other Figure 6B optical microscopy data, extracted from ImageJ as described in detail in the manuscript. The three datasets are for: a) 50 mM L-Asp only (measured in triplicate); b) 50 mM L-Asp + 15 mM D-Asp (measured in triplicate) and c) 50 mM L-Asp + 50 mM D-Asp (measured in duplicate). en public cc_by

Fig6B_data_time-lapse-optical-microscopy.xlsx

data 13513 3 41725 document 13513 FigS1_data_PXRD.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 0f5749cb3f2c9f1af0a8b2341716d996 MD5 205296 2020-09-09 11:49:26 https://researchdata.bath.ac.uk/905/4/FigS1_data_PXRD.xlsx 905 4 4 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other Powder X-ray diffraction data for Figure S1. Datasets (a) and (b) were extracted from I. Imaz, M. Rubio-Martínez, W. J. Saletra, D. B. Amabilino, D. Maspoch, J. Am. Chem. Soc. 2009, 131, 18222 for reference, while dataset (c) was collected experimentally as part of the present study. en public cc_by

FigS1_data_PXRD.xlsx

data 13514 3 41727 document 13514 FigS5_data_rheology2.xlsx application/vnd.openxmlformats-officedocument.spreadsheetml.sheet 1d9697c7b8e10a3dab7045d38f6dd9a4 MD5 10936 2020-09-09 11:51:57 https://researchdata.bath.ac.uk/905/5/FigS5_data_rheology2.xlsx 905 5 5 application/vnd.openxmlformats-officedocument.spreadsheetml.sheet other Rheology data for Figure S5, where G* and tan(delta) are presented as a function of D-Asp mole fraction in the range 0.1-0.5. en public cc_by

FigS5_data_rheology2.xlsx

data archive 12354 disk0/00/00/09/05 2020-10-02 12:31:24 2024-07-15 10:59:32 2020-10-02 12:31:24 data_collection show Engel Emile ee380@bath.ac.uk 0000-0001-6167-6432 University of Bath TRUE Calabrese Vincenzo V.Calabrese@bath.ac.uk 0000-0001-5974-9217 University of Bath FALSE Hossain Kazi M. Zakir zh603@bath.ac.uk 0000-0002-4178-7271 University of Bath FALSE Edler Karen K.Edler@bath.ac.uk 0000-0001-5822-0127 University of Bath FALSE Scott Janet L J.L.Scott@bath.ac.uk 0000-0001-8021-2860 University of Bath FALSE Dataset for "Composite hydrogel spheroids based on cellulose nanofibrils and nanofibrous chiral coordination polymer by green synthesis" GE0020 GE0040 dept_chem cellulose, hydrogel, coordination polymer, OCNF, nanocellulose This dataset contains data combined SAXS/WAXS data, rheology data, optical microscopy data (extracted using ImageJ) and powder X-ray diffraction data for hydrogel spheroids based on TEMPO-oxidised cellulose nanofibrils and a nanofibrous copper(II) aspartate coordination polymer. The data are provided in the form of Excel files and relate to figures presented in the main text and supplementary information of the publication "Composite hydrogel spheroids based on cellulose nanofibrils and nanofibrous chiral coordination polymer by green synthesis". The file "Fig3B_data_SAXS-WAXS.xlsx" contains combined SAXS and WAXS data for the main text Figure 3B, which comprises combined SAXS and WAXS patterns for pure Cu-Asp as reference (prepared in water) and OCNF dispersions containing L-Asp at the following concentrations: a) 0 mM (control sample), b) 50 mM, c) 75 mM, d) 100 mM and e) 125 mM. The file "Fig4_data_rheology1.xlsx" contains rheology data for the main text Figure 4, which comprises plots of G* and tan(delta) for OCNF dispersions containing L-Asp as a function L-Asp concentration in the range 0-150 mM. The file "Fig6B_data_time-lapse-optical-microscopy.xlsx" contains data for the main text Figure 6B from time lapse optical microscopy, extracted using ImageJ as detailed in the manuscript. Relative image darkness (proportional to crystallite density), d, is plotted as a function of time for 100 microL of OCNF dispersions with the following ligand concentrations: a) 50 mM L-Asp only (measured in triplicate); b) 50 mM L-Asp + 15 mM D-Asp (measured in triplicate) and c) 50 mM L-Asp + 50 mM D-Asp (measured in duplicate). The file "FigS1_data_PXRD.xlsx" contains powder X-ray diffraction (PXRD) data for the supplementary information Figure S1, where PXRD patterns are presented for: a) [Cu(L-Aspartate)]n; b) Cu(D-Aspartate)]n as described by I. Imaz, M. Rubio-Martínez, W. J. Saletra, D. B. Amabilino, D. Maspoch, J. Am. Chem. Soc. 2009, 131, 18222 (diffraction data extracted from the cited paper) and c) Cu-Asp prepared in water as a reference sample as part of the present study, from copper nitrate and L-Asp. The file "FigS5_data_rheology2.xlsx" contains rheology data for the supplementary information Figure S5, which comprises plots of G* and tan(delta) for OCNF dispersions containing 50 mM L-Asp (with 100 mM NaOH) and doped with D-Asp at concentrations of 0 mM to 50 mM (with 0 to 100 mM NaOH, accordingly) showing no considerable changes as a function of D-Asp mole fraction. 2020-09-30 University of Bath public RightsHolder University of Bath Commonwealth Scholarship Commission in the UK https://doi.org/10.13039/501100000867 ZARF-2017-473 Commonwealth Rutherford Fellowship Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/N033310/1 New Enzymatically Produced Interpenetrating Starch-Cellulose Gels University of Bath https://doi.org/10.13039/501100000835 cent_sus_tech A detailed description of materials and methods used in this study is presented in the manuscript main text under "Experimental Section" and the manuscript is available as open access. https://doi.org/10.1002/adsu.202000069 en 1 10.15125/BATH-00905 https://doi.org/10.1002/adsu.202000069 pub Scanning Electron Microscope (SEM) with Energy Dispersive X-Ray analyser (EDX) (JEOL JSM-6480LV) 894fff20-58e3-4787-9d81-99dcb6f32003 HR3 Discovery Hybrid Rheometer 9f2fdb2d-c645-45f3-be3d-b8e64f220c5d Small Angle X-Ray Scattering (SAXS) 328875d6-3504-48b5-89f5-ee59c4aec728 Powder X-Ray Diffractometer (PXRD) cedf86b0-97ba-46f4-839c-c2f5195cd898 Zetasizer 173af3f7-1ebd-4017-8b8f-54e9323f2d55 open