980 146 14888 3 46615 document 14888 Fig6.ogg audio/ogg 43d1f314c40f1417d85b8a8e2856b008 MD5 1687414 2021-04-27 11:27:44 https://researchdata.bath.ac.uk/980/24/Fig6.ogg 980 24 24 audio/ogg other Figure 6 shows the ^(31)P{^(23)Na} REAPDOR results for NAGP glass with x = 0. The Fourier transforms of S (top) and Delta S = S_0 - S (bottom) are plotted, where the spectra were obtained for a dipolar mixing time of 1.4 ms. Each spectrum is fitted to two Gaussian peaks. en public cc_by

Fig6.ogg

data 14889 3 46617 document 14889 Fig7a.ogg audio/ogg 31c2c8aabac5768029023bd65a5ec24b MD5 38904 2021-04-27 11:28:27 https://researchdata.bath.ac.uk/980/25/Fig7a.ogg 980 25 25 audio/ogg other Figure 7a shows the ^(31){P^(23)Na} REAPDOR data sets for as-prepared glassy and crystalline NAGP with x = 0. en public cc_by

Fig7a.ogg

data 14890 3 46622 document 14890 Fig7b.ogg audio/ogg e976ac82ae7e8485957050fa78838b4d MD5 66588 2021-04-27 11:29:36 https://researchdata.bath.ac.uk/980/26/Fig7b.ogg 980 26 26 audio/ogg other Figure 7(b) shows the ^(23){Na^(31)P} REDOR curves for as-prepared glassy and crystalline NAGP with x = 0. The solid curves show the fits to the NAGP data sets using Eq. 8. en public cc_by

Fig7b.ogg

data 14891 3 46624 document 14891 Fig8.ogg audio/ogg 428301ee78285eb8d05667d446ecc2ae MD5 6521577 2021-04-27 11:31:25 https://researchdata.bath.ac.uk/980/27/Fig8.ogg 980 27 27 audio/ogg other Figure 8 shows the single-pulse ^{27}Al MAS NMR spectra (black curves) measured for (a) as-prepared glassy, (b) annealed glassy and (c) crystalline NAGP with (I) x = 0.4 or (II) x = 0.8. en public cc_by

Fig8.ogg

data 14892 2 46630 document 14892 Fig9_ND_Sofk_crystal.agr text/plain 7f6898d293281b72d91368efb624b75e MD5 89971 2021-04-27 11:33:33 https://researchdata.bath.ac.uk/980/28/Fig9_ND_Sofk_crystal.agr 980 28 28 text/plain other Figure 9 shows the total structure factors S(k) for crystalline NAGP with x = 0, 0.4 and 0.8 measured using GEM [solid (red) curves] or D4c [solid (black) curves]. en public cc_by

Fig9_ND_Sofk_crystal.agr

data 14896 3 46641 document 14896 Fig11_NGP_Sofk_crystal_XRD.agr text/plain f27c50df655359e0a92767fff9d6977a MD5 59160 2021-04-27 11:47:33 https://researchdata.bath.ac.uk/980/30/Fig11_NGP_Sofk_crystal_XRD.agr 980 30 30 text/plain other Figure 11 shows the total structure factors S(k) for crystalline NAGP with x = 0, 0.4 and 0.8 measured using XRD. en public cc_by

Fig11_NGP_Sofk_crystal_XRD.agr

data 14897 2 46645 document 14897 Fig12_NGP_Sofk_glass_XRD.agr text/plain fd3b2501210b972e24f2a8179a6bbb37 MD5 109202 2021-04-27 11:48:19 https://researchdata.bath.ac.uk/980/31/Fig12_NGP_Sofk_glass_XRD.agr 980 31 31 text/plain other Figure 12 shows the total structure factors S(k) for as-prepared versus annealed glassy NAGP with x = 0, 0.4 and 0.8 measured using XRD. en public cc_by

Fig12_NGP_Sofk_glass_XRD.agr

data 14899 2 46651 document 14899 Fig13_NGP_Dofr_v3.agr text/plain 918b537b22f82684bb3e771c90c1e915 MD5 251884 2021-04-27 11:49:30 https://researchdata.bath.ac.uk/980/32/Fig13_NGP_Dofr_v3.agr 980 32 32 text/plain other Figure 13 shows the D^prime(r) functions for crystalline NAGP with x = 0 as obtained from the GEM data by the application of either a (a) Lorch or (b) step modification function with k_{max} = 39.1 A^{-1} and from (c) the XRD data by the application of a step modification function with k_{max} = 24.99 A^{-1}. en public cc_by

Fig13_NGP_Dofr_v3.agr

data 14900 2 46655 document 14900 Fig14_Dofr_fit_NGP_GEM_v2.agr text/plain d866319aa260ac2a5fb0a996f5f0a3fd MD5 507934 2021-04-27 11:50:05 https://researchdata.bath.ac.uk/980/33/Fig14_Dofr_fit_NGP_GEM_v2.agr 980 33 33 text/plain other Figure 14 shows the fitted D^prime(r) functions for (a) crystalline and (b) as-prepared glassy NAGP with x = 0 measured using GEM. en public cc_by

Fig14_Dofr_fit_NGP_GEM_v2.agr

data 14901 2 46658 document 14901 Fig15_Dofr_fit_NGP_XRD_v3.agr text/plain ad79ca74c0a5c370e8147a60bf4cb0a6 MD5 341840 2021-04-27 11:50:38 https://researchdata.bath.ac.uk/980/34/Fig15_Dofr_fit_NGP_XRD_v3.agr 980 34 34 text/plain other Figure 15 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0 measured using XRD. en public cc_by

Fig15_Dofr_fit_NGP_XRD_v3.agr

data 14902 2 46662 document 14902 Fig16_Dofr_fit_NGP_D4c_v3.agr text/plain 5cc0aa589323571f6257234e242266fa MD5 788086 2021-04-27 11:51:10 https://researchdata.bath.ac.uk/980/35/Fig16_Dofr_fit_NGP_D4c_v3.agr 980 35 35 text/plain other Figure 16 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0 measured using D4c. en public cc_by

Fig16_Dofr_fit_NGP_D4c_v3.agr

data 14904 2 46667 document 14904 Fig17_Dofr_fit_NGP04_GEM_v3.agr text/plain cc4040638d9b96e3d40b8f2009567efe MD5 453811 2021-04-27 11:51:42 https://researchdata.bath.ac.uk/980/36/Fig17_Dofr_fit_NGP04_GEM_v3.agr 980 36 36 text/plain other Figure 17 shows the fitted D^prime(r) functions for (a) crystalline and (b) as-prepared glassy NAGP with x = 0.4 measured using GEM. en public cc_by

Fig17_Dofr_fit_NGP04_GEM_v3.agr

data 14907 2 46676 document 14907 Fig18_Dofr_fit_NGP08_GEM_v3.agr text/plain 74596a0c724c6a5740d157686cb064fb MD5 454015 2021-04-27 11:52:22 https://researchdata.bath.ac.uk/980/37/Fig18_Dofr_fit_NGP08_GEM_v3.agr 980 37 37 text/plain other Figure 18 shows the fitted D^prime(r) functions for (a) crystalline and (b) as-prepared glassy NAGP with x = 0.8 measured using GEM. en public cc_by

Fig18_Dofr_fit_NGP08_GEM_v3.agr

data 14908 2 46679 document 14908 Fig19_Dofr_fit_NGP04_XRD_v4.agr text/plain cadeabbaae87ddc8acee2d0d28e42a79 MD5 385918 2021-04-27 11:52:57 https://researchdata.bath.ac.uk/980/38/Fig19_Dofr_fit_NGP04_XRD_v4.agr 980 38 38 text/plain other Figure 19 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0.4 measured using XRD. en public cc_by

Fig19_Dofr_fit_NGP04_XRD_v4.agr

data 14909 2 46684 document 14909 Fig20_Dofr_fit_NGP08_XRD_v4.agr text/plain fe181cbd4cf8b7e1475e84710c90532a MD5 386055 2021-04-27 11:53:33 https://researchdata.bath.ac.uk/980/39/Fig20_Dofr_fit_NGP08_XRD_v4.agr 980 39 39 text/plain other Figure 20 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0.8 measured using XRD. en public cc_by

Fig20_Dofr_fit_NGP08_XRD_v4.agr

data 14910 2 46687 document 14910 Fig21_Dofr_fit_NGP04_D4c_v4.agr text/plain 1265ea206296d97836ebd557c0204ae6 MD5 660119 2021-04-27 11:54:31 https://researchdata.bath.ac.uk/980/40/Fig21_Dofr_fit_NGP04_D4c_v4.agr 980 40 40 text/plain other Figure 21 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0.4 measured using D4c. en public cc_by

Fig21_Dofr_fit_NGP04_D4c_v4.agr

data 14911 2 46690 document 14911 Fig22_Dofr_fit_NGP08_D4c_v4.agr text/plain 192e94cac4ba46d1ecb49e6f491ca638 MD5 660188 2021-04-27 11:55:07 https://researchdata.bath.ac.uk/980/41/Fig22_Dofr_fit_NGP08_D4c_v4.agr 980 41 41 text/plain other Figure 22 shows the fitted D^prime(r) functions for (a) crystalline, (b) as-prepared glassy and (c) annealed glassy NAGP with x = 0.8 measured using D4c. en public cc_by

Fig22_Dofr_fit_NGP08_D4c_v4.agr

data 14912 2 46693 document 14912 Fig23_fNBO_vs_x_v13.agr text/plain 8f9434b865e0d10cfc4832ea8ff14790 MD5 57941 2021-04-27 11:55:37 https://researchdata.bath.ac.uk/980/42/Fig23_fNBO_vs_x_v13.agr 980 42 42 text/plain other Figure 23 shows the composition dependence of the (a) electrical conductivity sigma at 573 K and (b) activation energy E_a in crystalline versus as-prepared glassy NAGP (Ortiz-Mosquera et al. 2019, Zhang et al. 2009}, and (c)-(e) several of the parameters describing the NBO atoms in as-prepared versus annealed NAGP glasses. en public cc_by

Fig23_fNBO_vs_x_v13.agr

data 14941 3 46856 document 14941 Fig5.ogg audio/ogg 599232804fda93b3ab2d085996326ac9 MD5 6282234 2021-05-05 15:20:05 https://researchdata.bath.ac.uk/980/43/Fig5.ogg 980 43 43 audio/ogg other Figure 5 shows the single-pulse ^{31}P MAS NMR spectra measured for the NAGP materials with x = 0: (a) as-prepared glass; (b) glass annealed at T_{TT} = 873 K for 0.25 h; (c) glass annealed at T_{TT} = 876~K for 0.5 h; (d) crystalline material. en public cc_by

Fig5.ogg

data 14942 3 46858 document 14942 FigS1.ogg audio/ogg 9817a9c44006aa0cd1d2a38f3e2387ab MD5 2740572 2021-05-05 15:23:58 https://researchdata.bath.ac.uk/980/44/FigS1.ogg 980 44 44 audio/ogg other Figure S1 shows the single-pulse ^{31}P MAS NMR spectra (black curves) measured for (a) as-prepared glassy, (b) annealed glassy (T_{TT} = 873 K) and (c) crystalline NAGP with x = 0. en public cc_by

FigS1.ogg

data 14943 3 46860 document 14943 FigS2_Dofr_fit_NGP_D4c_603C_v2.agr text/plain f842f71511e336ca5169837ba1a3a18f MD5 1042981 2021-05-05 15:28:24 https://researchdata.bath.ac.uk/980/45/FigS2_Dofr_fit_NGP_D4c_603C_v2.agr 980 45 45 text/plain other Figure S2 shows the fitted D^prime(r) functions measured using D4c for NAGP with x = 0 annealed at T_{TT} = 876 K for either (a) 0.25 h or (b) 0.5 h. en public

FigS2_Dofr_fit_NGP_D4c_603C_v2.agr

data 14944 2 46867 document 14944 Fig10_ND_Sofk_glass_with_NGP_603C.agr text/plain 72f15e729f967899c3c1275b6054d75e MD5 205384 2021-05-05 16:19:31 https://researchdata.bath.ac.uk/980/46/Fig10_ND_Sofk_glass_with_NGP_603C.agr 980 46 46 text/plain other Figure 10 shows the total structure factors S(k) for as-prepared versus annealed glassy NAGP with x = 0, 0.4 and 0.8. The red curves give the GEM data sets and the black or blue curves give the D4c data sets, where the latter correspond to the x = 0 glass annealed at T_{TT} = 876~K for either 0.25 or 0.5~h. en public cc_by

Fig10_ND_Sofk_glass_with_NGP_603C.agr

data archive 479 disk0/00/00/09/80 2021-07-13 08:39:03 2024-07-15 10:59:40 2021-07-13 08:39:03 data_collection show Salmon Philip P.S.Salmon@bath.ac.uk 0000-0001-8671-1011 University of Bath TRUE Zeidler Anita A.Zeidler@bath.ac.uk 0000-0001-6501-8525 University of Bath TRUE ED0080 EM0050 EM0060 GE0030 GE0040 KS0160 dept_physics Data sets used to prepare Figures 5-23 and Figures S1-S2 in the Journal of Chemical Physics article entitled "Structure of crystalline and amorphous materials in the NASICON system Na_{1+x}Al_xGe_{2-x}(PO_4)_3 ." The data sets refer to the measured structure of these materials for the compositions x = 0, 0.4 and 0.8. NASICON is an acronym for sodium (Na) super-ionic conductor. 2021-07-13 University of Bath public RightsHolder University of Bath Royal Society https://doi.org/10.13039/501100000288 DH140152 Dorothy Hodgkin Research Fellowship - Rational Design of Glassy Materials with Technological Applications Engineering and Physical Sciences Research Council https://doi.org/10.13039/501100000266 EP/L015544/1 EPSRC Centre for Doctoral Training in Condensed Matter Physics Science and Technology Facilities Council https://doi.org/10.13039/501100000271 STU173 ISIS Facility Development Studentship (Lawrence Gammond) Diamond Light Source https://doi.org/10.13039/100011889 STU173 ISIS Facility Development Studentship (Lawrence Gammond) São Paulo Research Foundation (FAPESP) https://doi.org/10.13039/501100001807 2013/07793-6 Center for Research, Teaching, and Innovation in Glass São Paulo Research Foundation (FAPESP) https://doi.org/10.13039/501100001807 2017/17800-0 Postdoctoral Fellowship (Igor d’Anciães Almeida Silva) cent_nan cent_cmpcdt The data sets were collected using the methods described in the published paper. The data sets were analysed using the methods described in the published paper. Figures 5 - 8 and S1 were prepared using Origin (http://www.originlab.com/). The data set corresponding to a plotted curve within an Origin file can be identified by clicking on that curve. Figures 9 - 23 and S2 were prepared using QtGrace (https://sourceforge.net/projects/qtgrace/). The data set corresponding to a plotted curve within an QtGrace file can be identified by clicking on that curve. 2018-04-15 2021-05-01 en 1 10.15125/BATH-00980 https://doi.org/10.1063/5.0049399 pub