Data for cryocharging and cryokinetics analysis of hydrogen storage in MIL-101 (Cr) and AX-21.
Experimental data for testing of solid-state hydrogen storage materials. The tested materials included the highly porous and high-surface area metal-organic framework MIL-101 (Cr) and activated carbon AX-21, which were tested for hydrogen adsorption at high-pressures and cryogenic temperatures. Data includes amount of hydrogen adsorbed as a function of pressure, temperature and the kinetic data (amount adsorbed as a function of time). Dataset also includes the analysis files and the SEM imaging and treatment of the MIL-101 (Cr) and AX-21 samples.
Data for high-pressure hydrogen adsorption in MIL-101 (Cr) and AX-21. Includes:
- Excel files (.xlsx) with isotherm data as excess uptake of hydrogen in weight percent (mass of hydrogen divided by dry mass of sample) for the metal-organic framework material MIL-101 (Cr) at 77, 90, 100, 110, 130, 150, 200 and 292 K and up to 12 MPa and for the activated carbon AX-21 at 90, 100, 110, 120, 150, 200 and 298 K and up to 18 MPa.
- Excel files (.xlsx) with rational fits to the compressibility of hydrogen using the Leachman's equation of state for 77, 90, 100, 110, 120, 130, 150, 200, 292 and 298 K, up to 20 MPa.
- Excel files (.xlsx) with kinetic data for hydrogen excess uptake (micromols), pressure (MPa) and sample temperature (K) as a function of time for the MIL-101 (Cr) 77 and 90 K isotherm and for the AX-21 90 K isotherm.
- Origin files (.opj) with the analysis of the isotherm data for the cryocharging
- Origin files (.opj) with the analysis of the kinetic data using the linear driving force model
- Image files (.tif) for the SEM micrographs for the MIL-101 (Cr) and AX-21, and image files (.tif) for the particle analysis using Image J.
Manuscript for the results in this dataset (forthcoming): "High-pressure adsorptive storage of hydrogen in MIL-101 (Cr) and AX-21 for mobile applications: cryocharging and cryokinetics" by Nuno Bimbo, Wesley Xu, Jessica E Sharpe, Valeska P Ting and Timothy J Mays
Cite this dataset as:
Bimbo, N.,
Ting, V.,
2015.
Data for cryocharging and cryokinetics analysis of hydrogen storage in MIL-101 (Cr) and AX-21.
Bath: University of Bath Research Data Archive.
Available from: https://doi.org/10.15125/BATH-00099.
Export
Data
Isotherm_data … and_AX-21.xlsx
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet (18kB)
Kinetic_data … and_AX-21.xlsx
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet (384kB)
Cryocharging_analysis.opj
application/octet-stream (7MB)
Kinetic_analysis.opj
application/octet-stream (27MB)
AX-21_x_100.tif
image/tiff (4MB)
AX-21_x_100_(no_text).tif
image/tiff (4MB)
AX-21_-_bandpass_filter.tif
image/tiff (4MB)
AX-21_-_B&W.tif
image/tiff (4MB)
AX-21_-_particles.tif
image/tiff (4MB)
MIL-101_(Cr)_x_100.tif
image/tiff (4MB)
MIL-101_(Cr) … (no_text).tif
image/tiff (4MB)
MIL-101_(Cr)_-_bandpass_filter.tif
image/tiff (4MB)
MIL-101_(Cr)_-_B&W.tif
image/tiff (4MB)
MIL-101_(Cr)_-_particles.tif
image/tiff (4MB)
No restrictions.
Contributors
Tim Mays
Data Curator
University of Bath
Wesley Xu
Researcher
Jessica Sharpe
Researcher
University of Bath
Rights Holder
Coverage
Temporal coverage:
From 2010 to 2015
Documentation
Data collection method:
Experimental data was collected on a volumetric sorption apparatus Hiden HTP-1 (Hiden Isochema, Warrington, UK), with the isotherm data published previously (http://dx.doi.org/10.1007/s10450-013-9575-7). The experimental data in this dataset includes the isotherm data and the kinetic data, which is available from the equipment.
Data processing and preparation activities:
Isotherm and kinetic data were processed in Origin Pro 9.1 (OriginLab Corporation, Northampton, MA, USA). All the analysis files are available from this dataset. SEM images were analysed with Image J, with the results files also available from this dataset.
Funders
Engineering and Physical Sciences Research Council (EPSRC)
https://doi.org/10.13039/501100000266
Integrated safety strategies for onboard hydrogen storage systems
EP/K021109/1
Engineering and Physical Sciences Research Council (EPSRC)
https://doi.org/10.13039/501100000266
Hybrid Nanoporous Adsorption / High-pressure Gas Hydrogen Storage Tanks
EP/L018365/1
Engineering and Physical Sciences Research Council (EPSRC)
https://doi.org/10.13039/501100000266
Hydrogen and Fuel Cell Hub
EP/J016454/1
Publication details
Publication date: 8 June 2015
by: University of Bath
Version: 1
DOI: https://doi.org/10.15125/BATH-00099
URL for this record: https://researchdata.bath.ac.uk/id/eprint/99
Related papers and books
Bimbo, N., Sharpe, J. E., Ting, V. P., Noguera-Díaz, A., and Mays, T. J., 2013. Isosteric enthalpies for hydrogen adsorbed on nanoporous materials at high pressures. Adsorption, 20(2-3), 373-384. Available from: https://doi.org/10.1007/s10450-013-9575-7.
Bimbo, N., Xu, W., Sharpe, J. E., Ting, V. P., and Mays, T. J., 2016. High-pressure adsorptive storage of hydrogen in MIL-101 (Cr) and AX-21 for mobile applications: Cryocharging and cryokinetics. Materials & Design, 89, 1086-1094. Available from: https://doi.org/10.1016/j.matdes.2015.10.069.
Related online resources
Bimbo, N., Xu, W., Sharpe, J. E., Ting, V. P., and Mays, T. J., 2016. Corrigendum to “High-pressure adsorptive storage of hydrogen in MIL-101 (Cr) and AX-21 for mobile applications: Cryocharging and cryokinetics” [Mater & Des 89 (2016) 1086–1094]. Materials & Design, 91, 440. Available from: https://doi.org/10.1016/j.matdes.2015.11.118.
Contact information
Please contact the Research Data Service in the first instance for all matters concerning this item.
Contact person: Nuno Bimbo
Faculty of Engineering & Design
Chemical Engineering
