Data for Iron-Catalyzed Transfer Hydrogenation of Allylic Alcohols with Ethanol at Near Room Temperature

Data collection method:

Full experimental details for the preparation of each compound can be found in the Supplementary Information of the associated paper.

Technical details and requirements:

1H NMR, 13C NMR and 19F NMR spectra were obtained on a Bruker Avance, a Bruker Avance 400 (400 MHz 1H, 101 MHz 13C, 376 MHz 19F) or a Bruker Avance 500 (500 MHz 1H, 126 MHz 13C, 471 MHz 19F) spectrometer at room temperature in the solvent stated. Infrared spectra were recorded on a Shimadzu IRAffinity-1 Fourier Transform ATIR spectrometer as thin films using a Pike MIRacle ATR accessory. High-resolution mass spectrometric (HRMS) data were obtained on a Waters MALDI-TOF mx in Cardiff University.

Additional information:

NMR data are presented in the following format: chemical shift (multiplicity [s = singlet, br = broad, d = doublet, t = triplet, q = quartet, p = pentet dd = doublet of doublets, dt = doublet of triplets, dq = doublet of quartets, ddd = doublet of doublet of doublets, m = multiplet], coupling constant [in Hz], number of equivalent nuclei by integration). Spin-spin coupling constants J are given in Hz and refer to apparent multiplicities rather than true coupling constants. Data are reported as: chemical shift, multiplicity and integration. Infrared spectra were recorded with absorbance peaks quoted (νmax/cm-1).