Dataset for 'Exploring effects of intermittent light upon visible light promoted water oxidations'
Visible light promoted photocatalytic water oxidations for potential solar fuel production have been studied widely, with many reports on optimization of reagent components. Here we report an exploration on the effects upon ongoing reactions of daylight equivalent light intensity illumination with regulated short dark periods of a few seconds duration as compared to standard continuous illumination.
In addition raw XRD data of metal oxide catalysts used, an additional image of reaction flask and a movie file that shows a reaction flask under under cycling RGB LED illumination is given here.
Cite this dataset as:
Walsh, D.,
2018.
Dataset for 'Exploring effects of intermittent light upon visible light promoted water oxidations'.
Bath: University of Bath Research Data Archive.
Available from: https://doi.org/10.15125/BATH-00470.
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Data
XRD-CaMnOX.txt
text/plain (49kB)
Creative Commons: Attribution 4.0
XRD-Co3O4.csv
text/plain (33kB)
Creative Commons: Attribution 4.0
XRD-Fe2O3.txt
text/plain (20kB)
Creative Commons: Attribution 4.0
led_emission.mantid
text/plain (38kB)
Creative Commons: Attribution 4.0
Flask_and_vial.jpg
image/jpeg (466kB)
Creative Commons: Attribution 4.0
Photoreaction … coloured_light.MOV
video/quicktime (132MB)
Creative Commons: Attribution 4.0
Creators
Dominic Walsh
University of Bath
Contributors
Pascaline Patureau
Researcher
University of Bath
Karen Robertson
Researcher
University of Bath
Shaun Reeksting
Researcher
University of Bath
Anneke Lubben
Researcher
University of Bath
Salvador Eslava
Project Member
University of Bath
Mark T Weller
Project Member
University of Bath
University of Bath
Rights Holder
Coverage
Collection date(s):
From February 2016 to September 2017
Documentation
Data collection method:
Details of the methodology used to collect this data can be found in the associated manuscript, published in RSC Sustainable Energy and Fuels (DOI: 10.1039/C7SE00304H).
Additional information:
A movie file is provided that shows illumination of a reaction flask with light harvester and metal oxide catalyst, a cycling RGB led light source is used. Under red light the iron oxide catalyst and [Ru[bpy)3]2+ light harvester reflects the incoming light. Blue light is adsorbed as shown by the visible darkening of the stirred reaction mixture.
Methodology link:
Walsh, D., Patureau, P., Robertson, K., Reeksting, S., Lubben, A., Eslava, S., and Weller, M. T., 2017. Exploring effects of intermittent light upon visible light promoted water oxidations. Sustainable Energy & Fuels, 1(10), 2101-2109. Available from: https://doi.org/10.1039/c7se00304h.
Funders
Engineering and Physical Sciences Research Council (EPSRC)
https://doi.org/10.13039/501100000266
Nanostructured Metal Oxides for Solar Fuels
EP/P008097/1
Publication details
Publication date: 6 February 2018
by: University of Bath
Version: 1
DOI: https://doi.org/10.15125/BATH-00470
URL for this record: https://researchdata.bath.ac.uk/id/eprint/470
Related papers and books
Walsh, D., Patureau, P., Robertson, K., Reeksting, S., Lubben, A., Eslava, S., and Weller, M. T., 2017. Exploring effects of intermittent light upon visible light promoted water oxidations. Sustainable Energy & Fuels, 1(10), 2101-2109. Available from: https://doi.org/10.1039/c7se00304h.
Contact information
Please contact the Research Data Service in the first instance for all matters concerning this item.
Contact person: Dominic Walsh
Faculty of Engineering & Design
Chemical Engineering
Faculty of Science
Chemistry
