Dataset for "Antagonistic Mixing in Micelles of Amphiphilic Polyoxometalates and Hexaethylene Glycol Monododecyl Ether"

The dataset contains ASCII files for the following:

- Small-angle neutron scattering (SANS) curves and fits for mixtures (mole ratios: 3:1, 1:1 and 1:3) containing polyoxometalate-headed surfactant(P2W17-2Cn, n= 12, 14, 16 and 18) and hydrogenated hexaethylene glycol monododecyl ether (C12EO6) as a function of surfactant total concentrations. Solutions are prepared in two different solvents: deuterium dioxide, 7:3 deuterium dioxide and H2O mixture.

- SANS curves and fits for mixtures containing P2W17-2Cn surfactant (n = 12 and 14) and tail-deuterated C12EO6 (mole ratios: 3:1, 1:1 and 1:3) as a function of surfactant total concentrations. Solutions are prepared in deuterium dioxide.

The dataset also contains Igor files for the following:

- The plot of determination of critical micelle concentrations (CMC) of the mixed P2W17-2Cn/C12EO6 H2O system through surface tension measurements and conductivity measurements.

Keywords:
polyoxometallate amphiphiles, hexaethylene glycol monododecyl ether, unfavourable mixing, micellar composition, small angle neutron scattering
Subjects:

Cite this dataset as:
Di, A., Schmitt, J., Ma, K., Alves Da Silva, M., Elstone, N., Mahmoudi, N., Li, P., Washington, A., Wang, Z., Errington, J., Edler, K., 2020. Dataset for "Antagonistic Mixing in Micelles of Amphiphilic Polyoxometalates and Hexaethylene Glycol Monododecyl Ether". Bath: University of Bath Research Data Archive. Available from: https://doi.org/10.15125/BATH-00845.

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Data

JCIS data archive.zip
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Creative Commons: Attribution 4.0

Data archive for "Antagonistic Mixing in Micelles of Amphiphilic Polyoxometalates and Hexaethylene Glycol Monododecyl Ether"

Creators

Andi Di
University of Bath

Julien Schmitt
University of Bath

Kun Ma
Science and Technology Facilities Council

Naomi Elstone
University of Bath

Najet Mahmoudi
Science and Technology Facilities Council

Peixun Li
Science and Technology Facilities Council

Adam Washington
Science and Technology Facilities Council

Zi Wang
Science and Technology Facilities Council

John Errington
Newcastle University

Karen Edler
University of Bath

Contributors

University of Bath
Rights Holder

Documentation

Data collection method:

SANS experiments were performed on the LOQ and LARMOR instruments in Target Station I and II, respectively at the ISIS Neutron and Muon Spallation Source, Oxfordshire, UK. The samples were measured in 1 cm wide, 1 mm path-length optical quartz cells at 25 degree C, using a thermostat-controlled circulating bath. Samples were measured for 40 μA (D2O) and 80 μA (70 mol% D2O) of neutron current on the LOQ instrument. For experiments on LARMOR, mixtures containing P2W17-2Cn with d-C12EO6 in D2O were measured for 20 μA. The raw data were corrected for sample transmission and backgrounds from the solvent, the sample cell and other instrumental background using standard workflows in the Mantid software package. Scattering data were normalised against the scattering from a partially-deuterated polystyrene blend of known molecular weight, converting it to the differential scattering cross section d/d(q) (in an absolute scale of cm-1). The output data are hence given in absolute scattered intensity, I(q) in cm-1, versus the momentum transfer, q in Å-1. The CMC of the C12EO6 in water was measured using a Du Noüy Ring (Attension Sigma 701 Tensiometer). The CMCs of the binary systems were measured by either conductivity using a METTLER TOLEDO conductivity meter or by a pendant-drop method using a Kruss DSA100 at Diamond Light Source. For P2W17-2Cn-rich mixtures, electrical conductivity measurements give CMC values with more accuracy, whereas surface tension measurements provide more accurate results for the C12EO6-rich mixtures.

Funders

China Scholarship Council
https://doi.org/10.13039/501100004543

Publication details

Publication date: 10 June 2020
by: University of Bath

Version: 1

DOI: https://doi.org/10.15125/BATH-00845

URL for this record: https://researchdata.bath.ac.uk/id/eprint/845

Related papers and books

Di, A., Schmitt, J., Ma, K., da Silva, M. A., Elstone, N. S., Mahmoudi, N., Li, P., Washington, A., Wang, Z., Errington, R. J., and Edler, K. J., 2020. Antagonistic mixing in micelles of amphiphilic polyoxometalates and hexaethylene glycol monododecyl ether. Journal of Colloid and Interface Science, 578, 608-618. Available from: https://doi.org/10.1016/j.jcis.2020.06.007.

Contact information

Please contact the Research Data Service in the first instance for all matters concerning this item.

Contact person: Andi Di

Departments:

Faculty of Science
Chemistry