Degradation of a β-O-4 model lignin species by vanadium Schiff-base catalysts: influence of catalyst structure and reaction conditions on activity and selectivity

Degradation of a β-O-4 model lignin species by vanadium Schiff-base catalysts: influence of catalyst structure and reaction conditions on activity and selectivity

The paper describes a way methodology for the depolymerisation of lignin (wood) and the uploaded data is the methodology that we used to generate the data in the presented in the paper.

The data uploaded is the raw data so that the reader can follow the procedure we used for the determination of the rate constants and activation energies in the papers

Cite this dataset as:
Jones, M., 2015. Degradation of a β-O-4 model lignin species by vanadium Schiff-base catalysts: influence of catalyst structure and reaction conditions on activity and selectivity. University of Bath. https://doi.org/10.15125/BATH-00135.

Export

Data

Arrhenius_data_ ... _Cat_Paper.xlsx
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet (58kB)

Catalyst_loadin ... _cat_paper.xlsx
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet (74kB)

Creators

Contributors

Heather Parker
Data Collector

Timothy Woodman
Data Collector

Christopher Chuck
Data Collector

University of Bath
Rights Holder

Documentation

Data collection method:

The data was determined from 1H NMR spectroscopic measurements using the procedure determined in the paper. There are two excel files which contain the raw data for the determination of rate constants. We used a simple pseudo first order approach and plotted the natural log of concentration vs time and the gradient in the first order rate constant. We also plotted the natural log of k vs 1/T to give us the activation energy.

Funders

Engineering and Physical Sciences Research Council (EPSRC)
https://doi.org/10.13039/501100000266

Doctoral Training Centre in Sustainable Chemical Technologies
EP/G03768X/1

Publication details

Publication date: 2015
by: University of Bath

Version: 1

DOI: https://doi.org/10.15125/BATH-00135

URL for this record: https://researchdata.bath.ac.uk/id/eprint/135

Related articles

Parker, H. J., Chuck, C. J., Woodman, T. and Jones, M. D., 2016. Degradation of β-O-4 model lignin species by vanadium Schiff-base catalysts: Influence of catalyst structure and reaction conditions on activity and selectivity. Catalysis Today, 269, pp.40-47. Available from: https://doi.org/10.1016/j.cattod.2015.08.045.

Contact information

Please contact the Research Data Service in the first instance for all matters concerning this item.

Contact person: Matthew Jones

Departments:

Faculty of Engineering & Design
Chemical Engineering

Faculty of Science
Chemistry
Pharmacy & Pharmacology