Experimental Crystal Structure Determinations for "Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl"
Although the nucleophilic alkylation of aromatics has recently been achieved with a variety of potent main group reagents, all of this reactivity is limited to a stoichiometric regime. This collection contains Experimental Crystal Structure Determinations used in support of a study indicating that the ytterbium(II) hydride, [BDI^{Dipp}YbH]₂ (BDI^{Dipp} = CH[C(CH₃)NDipp]₂, Dipp = 2,6-diisopropylphenyl), reacts with ethene and propene to provide the ytterbium(II) n-alkyls, [BDIDippYbR]₂ (R = Et or Pr), both of which alkylate benzene at room temperature.
Cite this dataset as:
Richardson, G.,
Douair, I.,
Cameron, S.,
Bracegirdle, J.,
Keyzers, R.,
Hill, M.,
Maron, L.,
Anker, M.,
2021.
Experimental Crystal Structure Determinations for "Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl".
Cambridge Crystallographic Data Centre.
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Creators
Georgia Richardson
Victoria University of Wellington
Iskander Douair
University of Toulouse
Scott Cameron
Victoria University of Wellington
Joe Bracegirdle
Victoria University of Wellington
Robert Keyzers
Victoria University of Wellington
Michael Hill
University of Bath
Laurent Maron
University of Toulouse
Mathew Anker
Victoria University of Wellington
Contributors
University of Bath
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Documentation
Data collection method:
The methodology can be found in the associated paper.
Methodology link:
Richardson, G. M., Douair, I., Cameron, S. A., Bracegirdle, J., Keyzers, R. A., Hill, M. S., Maron, L., and Anker, M. D., 2021. Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl. Nature Communications, 12(1). Available from: https://doi.org/10.1038/s41467-021-23444-x.
Funders
Victoria University of Wellington
https://doi.org/10.13039/501100001538
Publication details
Publication date: 25 May 2021
by: Cambridge Crystallographic Data Centre
Version: 1
URL for this record: https://researchdata.bath.ac.uk/id/eprint/1426
Related papers and books
Richardson, G. M., Douair, I., Cameron, S. A., Bracegirdle, J., Keyzers, R. A., Hill, M. S., Maron, L., and Anker, M. D., 2021. Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl. Nature Communications, 12(1). Available from: https://doi.org/10.1038/s41467-021-23444-x.
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Please contact the Research Data Service in the first instance for all matters concerning this item.
Faculty of Science
Chemistry
Research Centres & Institutes
Centre for Doctoral Training in Aerosol Science
Centre for Sustainable and Circular Technologies (CSCT)
