Dataset for "Understanding the AC conductivity and permittivity of trapdoor chabazites for future development of next-generation gas sensors"

Synthetic K+ chabazite (KCHA), Cs+ chabazite (CsCHA) and Zn2+ chabazite (ZnCHA) were synthesized and compared in order to relate the differences in their crystalline structures to their thermal stability (TGA data), moisture content (TGA data) and frequency dependent alternating current (AC) conductivity (AC conductivity heating and cooling data), permittivity (permittivity heating and cooling data) and phase angle (phase angle heating and cooling data) at a range of temperatures. Cation migration activation energies for KCHA (0.66 ± 0.10) eV, CsCHA (0.88 ± 0.01) eV and ZnCHA (0.90 ± 0.01) eV were determined (activation energy data). Good thermal stability of the materials was observed up to 710 °C (TGA data) and below 200 °C the electrical properties were strongly influenced by hydration level (conductivity, permittivity and phase angle data). Overall, it was determined that when either hydrated or dehydrated, KCHA had the highest conductivity and lowest cation migration activation energy of the three studied chabazites (activation energy data).

Cite this dataset as:
Bordeneuve, H., Wales, D., Physick, A., Doan, H., Ting, V., Bowen, C., 2017. Dataset for "Understanding the AC conductivity and permittivity of trapdoor chabazites for future development of next-generation gas sensors". Bath: University of Bath Research Data Archive. Available from: https://doi.org/10.15125/BATH-00402.

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Data

Open_Access_Dataset.zip
application/zip (2MB)
Creative Commons: Attribution 4.0

Creators

Hélène Bordeneuve
University of Bath

Dominic Wales
University of Bath

Andrew Physick
University of Bath

Huan Doan
University of Bristol; Hanoi University of Mining and Geology

Valeska Ting
University of Bristol

Chris Bowen
University of Bath

Contributors

University of Bath
Rights Holder

Coverage

Collection date(s):

2017

Documentation Files

Dataset_Information.pdf
application/pdf (535kB)
Creative Commons: Attribution 4.0

Funders

Seventh Framework Programme
https://doi.org/10.13039/501100004963

NEMESIS - Novel Energy Materials: Engineering Science and Integrated Systems
320963

European Regional Development Fund
https://doi.org/10.13039/501100008530

Materials for Energy Efficient Transport (MEET)
EP/K503575/1/UNIQUIP

Engineering and Physical Sciences Research Council
https://doi.org/10.13039/501100000266

United Kingdom Sustainable Hydrogen Energy Consortium (UK-SHEC) CORE Programme
EP/E040071/1

Publication details

Publication date: 2017
by: University of Bath

Version: 1

DOI: https://doi.org/10.15125/BATH-00402

URL for this record: https://researchdata.bath.ac.uk/id/eprint/402

Related papers and books

Bordeneuve, H., Wales, D. J., Physick, A. J.W., Doan, H. V., Ting, V. P., and Bowen, C. R., 2018. Understanding the AC conductivity and permittivity of trapdoor chabazites for future development of next-generation gas sensors. Microporous and Mesoporous Materials, 260, 208-216. Available from: https://doi.org/10.1016/j.micromeso.2017.10.032.

Contact information

Please contact the Research Data Service in the first instance for all matters concerning this item.

Contact person: Chris Bowen

Departments:

Faculty of Engineering & Design
Electronic & Electrical Engineering
Mechanical Engineering