Data set for: Mo-doped TiO2 photoanodes using [Ti4Mo2O8(OEt)10]2 bimetallic oxo cages as a single source precursor

Data collection method:

See document attached for specific details of the data collection method.

Additional information:

The data, with the exception of the EPR data, are presented as tab-separated value (TSV) files. The convention used for the headings of the columns is Mo:TiO2-XXX where XXX is the annealing temperature employed during the preparation of the samples (as described in the experimental section of the manuscript). The detailed convention method used for each technique, with the corresponding units, is as follows: - X-Ray diffraction: x_Mo-TiO2-XXX (x axis, Units: 2theta), y_Mo:TiO2-XXX (y axis, Units: Intensity/arbitrary units) - Raman spectroscopy: Mo:TiO2-XXX_W (x axis, Units: Raman Shift/cm^-1), Mo:TiO2-XXX-I (y axis, Units: Intensity/arbitrary units) - XPS_single scan: Mo:TiO2-XXX_Y_BE where Y is the corresponding element analysed (i.e. Ti, O or Mo) (x axis, Units: Binding Energy/eV), Mo:TiO2-XXX_Y_I (y axis, Units: Intensity/arbitrary units). In this set of data there are additional columns belonging to the deconvoluted peaks of each element studied, labelled as Mo:TiO2-XXX-Y-P1 - XPS Survey Analysis: Mo:TiO2-XXX_BE (x axis, Units: Binding Energy/eV), Mo:TiO2-XXX-Survey (y axis, Units: Intensity/arbitrary units) - EPR: There is one file per sample studied. These files contain tables with fixed-width fields, and are therefore best viewed as plain text with a fixed-width typeface. - UV-Vis: eV (x axis, Units: Energy/eV) , Mo:TiO2-XXX_KM (y axis, Units: F(R)E^1/2) - J-V curves: E_Mo-TiO2-XXX (x axis, Units: E vs RHE), J_Mo:TiO2_XXX (y axis, Units: Photocurrent density/mA cm^-2) - J-Time curves: Time (x axis, Units: Time/seconds), J_Mo:TiO2-XXX (y axis, Units: Photocurrent density/mA cm^-2) - Nyquist plots: Mo:TiO2-XXX_ R (x axis, Units: Real part/ohms), Mo:TiO2-XXX-I (y axis, Units: Imaginary part/ohms)