Data set for "Surfactant Effects on the Synthesis of Porous Cerium Oxide from a Type IV Deep Eutectic Solvent"
This dataset relates to a novel, low temperature and green method for atom-efficient solvothermal synthesis of crystalline, micelle templated cerium IV oxide (ceria) from a type IV deep eutectic solvent (DES) comprising a hydrated cerium containing metal salt, cerium(iii) nitrate hexahydrate (Ce(NO₃)₃·6H₂O), and a hydrogen bond donor, urea, in a molar ratio of 1:3.5. We have used high concentration (20% w/w) solutions of C-12 and C-16 alkyl chain length cationic surfactants (CₙTAB and CₙTANO₃) and C-16 alkyl chain length non-ionic surfactant BrijC₁₀ in the DES to alter the porosity of the cerium oxide produced. The characterisation of the cerium oxide has been carried out using scanning and transmission electron microscopy (SEM/TEM), N₂ sorption, Small Angle X-ray Scattering (SAXS) and temperature programmed reduction (TPR) to understand and quantify the nature of the crystallinity, morphology and porosity along with CO oxidation for the catalytic activity of the material.
Included in the dataset are the X-ray diffraction (XRD), SAXS, N₂ sorption, SEM Energy Dispersive X-Ray Analysis (EDX), X-ray photoelectron (XPS) and CO oxidation characterization data for these materials.
Cite this dataset as:
Manasi, I.,
Castaing, R.,
Edler, K.,
Andalibi, M.,
2022.
Data set for "Surfactant Effects on the Synthesis of Porous Cerium Oxide from a Type IV Deep Eutectic Solvent".
Bath: University of Bath Research Data Archive.
Available from: https://doi.org/10.15125/BATH-01190.
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Data
SAXS_paper.zip
application/zip (399kB)
Creative Commons: Attribution 4.0
SAXS data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 2b in the paper.
XRD paper.zip
application/zip (245kB)
Creative Commons: Attribution 4.0
XRD data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 1c & 5a and Table S1 & S2 in the paper and its supplementary information.
N2sorption_paper.zip
application/zip (35kB)
Creative Commons: Attribution 4.0
N₂ data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 2a & 5b in the paper.
CO oxidation_paper.zip
application/zip (2MB)
Creative Commons: Attribution 4.0
CO oxidation data from mesoporous cerium oxide. There is an Excel file that gives the key to the data. Data corresponds to Figure 4, 6c & S4 in the paper and its supplementary information.
XPS_CeOx_Data.xlsx
application/vnd.openxmlformats-officedocument.spreadsheetml.sheet (768kB)
Creative Commons: Attribution 4.0
XPS data from mesoporous cerium oxide. One of the worksheets provides the key to the data. Data corresponds to Figure S5 in the paper's supplementary information.
SEM_EDX_paper.zip
application/zip (11MB)
Creative Commons: Attribution 4.0
SEM EDX data from mesoporous cerium oxide. There is an Excel file that gives the key to the data.
TPR data_paper.zip
application/zip (157kB)
Creative Commons: Attribution 4.0
TPR data from mesoporous cerium oxide. There is an Excel file that gives the key to the data.
Creators
Iva Manasi
University of Bath
Rémi Castaing
University of Bath
Karen Edler
University of Bath
Mohammad Andalibi
University of Cambridge
Contributors
University of Bath
Rights Holder
Documentation
Data collection method:
Full details of the methodology can be found in the Materials and Methods section of the associated paper.
Additional information:
Each ZIP file contains an MS Excel spreadsheet that provides details of the samples identified by number in the data file names. In "SAXS_paper.zip", the .dat files are comma-separated value (CSV) plain text files. In "XRD paper.zip", the .raw files are STOE RAW Powder X-ray diffraction files (from a STOE STADI P instrument) and the .xyd files are fixed-width field plain text files.
Methodology link:
Manasi, I., Andalibi, M. R., Castaing, R., Torrente-Murciano, L., and Edler, K. J., 2022. Surfactant effects on the synthesis of porous cerium oxide from a type IV deep eutectic solvent. Journal of Materials Chemistry A, 10(35), 18422-18430. Available from: https://doi.org/10.1039/d2ta05693c.
Funders
Engineering and Physical Sciences Research Council
https://doi.org/10.13039/501100000266
Enabling industrial deployment of deep eutectic solvents through manufacturing tools
EP/S020772/1
Engineering and Physical Sciences Research Council
https://doi.org/10.13039/501100000266
Enabling industrial deployment of deep eutectic solvents through manufacturing tools
EP/S021019/1
Publication details
Publication date: 8 August 2022
by: University of Bath
Version: 1
DOI: https://doi.org/10.15125/BATH-01190
URL for this record: https://researchdata.bath.ac.uk/id/eprint/1190
Related papers and books
Manasi, I., Andalibi, M. R., Castaing, R., Torrente-Murciano, L., and Edler, K. J., 2022. Surfactant effects on the synthesis of porous cerium oxide from a type IV deep eutectic solvent. Journal of Materials Chemistry A, 10(35), 18422-18430. Available from: https://doi.org/10.1039/d2ta05693c.
Contact information
Please contact the Research Data Service in the first instance for all matters concerning this item.
Contact person: Iva Manasi
Faculty of Science
Chemistry
